Abstract
The use of chiral ligand-modified metal nanoparticles is a promising strategy for constructing active and robust asymmetric catalyst systems. A recent advance in such catalyst systems for C−C bond-forming reactions is highlighted, and the characteristics of the active species are discussed. Several studies suggested that a redox event between nanoparticles and reagents might be a key to generating active species from nanoparticles.
Original language | English |
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Pages (from-to) | 7979–7988 |
Number of pages | 10 |
Journal | ACS Catalysis |
Volume | 6 |
Issue number | 11 |
DOIs | |
Publication status | Published - 4 Nov 2016 |
Externally published | Yes |
Keywords
- Asymmetric catalysis
- Bifunctional ligand
- C−C bond-forming reactions
- Dual catalysis
- Heterogeneous catalyst
- Metal nanoparticle