TY - JOUR
T1 - Cationic aluminium hydrides
T2 - [H2AlL]+[AlH 4]-, L = N,N,N′,N′,N′- pentamethyldiethylenetriamine and 1,4,8,11-tetramethyl-1,4,8,11- tetraazacyclotetradecane
AU - Atwood, Jerry L.
AU - Robinson, Kerry D.
AU - Jones, Cameron
AU - Raston, Colin L.
PY - 1991/12/1
Y1 - 1991/12/1
N2 - Reaction of H3AlNMe3 with N,N,N′,N″, N″-pentamethyldiethylenetriamine (pmdien) in diethyl ether or 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (Me4cyclam) in tetrahydrofuran yields [H2Al(pmdien)]+ [AlH 4]-, which possesses a trigonal bipyramidal cation with the hydrides in the trigonal plane [Al-N′ 2.158(7), Al-N,N″ 2.01(1), Al-H 1.62 Å] or [H2Al(Me4 cyclam)] +[AlH4], where the metal centre in the cation is trans-octahedral [Al-N(mean) 2.13, Al-H 1.60, 1.64 Å].
AB - Reaction of H3AlNMe3 with N,N,N′,N″, N″-pentamethyldiethylenetriamine (pmdien) in diethyl ether or 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane (Me4cyclam) in tetrahydrofuran yields [H2Al(pmdien)]+ [AlH 4]-, which possesses a trigonal bipyramidal cation with the hydrides in the trigonal plane [Al-N′ 2.158(7), Al-N,N″ 2.01(1), Al-H 1.62 Å] or [H2Al(Me4 cyclam)] +[AlH4], where the metal centre in the cation is trans-octahedral [Al-N(mean) 2.13, Al-H 1.60, 1.64 Å].
UR - https://www.scopus.com/pages/publications/37049066765
U2 - 10.1039/C39910001697
DO - 10.1039/C39910001697
M3 - Article
AN - SCOPUS:37049066765
SN - 0022-4936
SP - 1697
EP - 1699
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 23
ER -