Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition

David M. Hodgson; Paul A. Stupple; Craig Johnstone

doi:10.1016/S0040-4039(97)01480-9

Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition

David M. Hodgson, Paul A. Stupple, Craig Johnstone

Research output: Contribution to journal › Article › Research › peer-review

96 Citations (Scopus)

Abstract

Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition of α-diazo-β-ketoesters 1 (R = alkyl, n = 1,2) using 1 mol% [Rh₂(S-DOSP)₄] 2 in hexane at room temperature to give the cycloadducts 3 in good yields and up to 53% ee are described.

Original language	English
Pages (from-to)	6471-6472
Number of pages	2
Journal	Tetrahedron Letters
Volume	38
Issue number	36
DOIs	https://doi.org/10.1016/S0040-4039(97)01480-9
Publication status	Published - 8 Sept 1997
Externally published	Yes

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title = "Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition",

abstract = "Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition of α-diazo-β-ketoesters 1 (R = alkyl, n = 1,2) using 1 mol% [Rh2(S-DOSP)4] 2 in hexane at room temperature to give the cycloadducts 3 in good yields and up to 53% ee are described.",

author = "Hodgson, {David M.} and Stupple, {Paul A.} and Craig Johnstone",

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T1 - Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition

AU - Hodgson, David M.

AU - Stupple, Paul A.

AU - Johnstone, Craig

PY - 1997/9/8

Y1 - 1997/9/8

N2 - Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition of α-diazo-β-ketoesters 1 (R = alkyl, n = 1,2) using 1 mol% [Rh2(S-DOSP)4] 2 in hexane at room temperature to give the cycloadducts 3 in good yields and up to 53% ee are described.

AB - Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition of α-diazo-β-ketoesters 1 (R = alkyl, n = 1,2) using 1 mol% [Rh2(S-DOSP)4] 2 in hexane at room temperature to give the cycloadducts 3 in good yields and up to 53% ee are described.

UR - http://www.scopus.com/inward/record.url?scp=0030840478&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(97)01480-9

DO - 10.1016/S0040-4039(97)01480-9

M3 - Article

AN - SCOPUS:0030840478

SN - 0040-4039

VL - 38

SP - 6471

EP - 6472

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 36

ER -

Catalytic enantioselective tandem carbonyl ylide formation-cycloaddition

Abstract

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