Carboxylated nanocellulose foams as superabsorbents

Llyza Mendoza, Laila Hossain, Emma Downey, Camilla Scales, Warren Batchelor, Gil Garnier

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Hypothesis: Carboxylated nanocellulose fibres formed into foam structures can demonstrate superabsorption capacity. Their performance can be engineered by changing process variables. Experiments: TEMPO-oxidised cellulose nanofibres of varying concentration and surface charge are produced from hardwood kraft pulp. Foams were prepared through a 2-step freezing and lyophilisation process. The absorption capacity of water and saline solution (0.9 wt%) were measured as a function of time and related to the foam structure. Findings: The absorption capacity of nanocellulose foams can be manipulated from initial gel properties and processing conditions. Pore structure and distribution of nanocellulose foams are dictated by fibre content and charge density and freezing rate. The best performing foams are at 0.3–0.5 wt%, with a carboxylate concentration of 1.2 mmol/g and frozen at −86 °C before freeze-drying, which can absorb 120 g H2O/g fibre. Fibre surface charge influences the absorption capacity of the foams by dictating the amount of participating carboxylate groups. Absorption capacity in saline (60 g/g) is lower than in deionised water (120 g/g); but is only slightly lower than that of a commercial polyacrylic acid (PAA) SAPs (80 g/g). Nanocellulose foams are attractive renewable alternatives for superabsorbent applications, contributing to a reduction of plastic microspheres.

Original languageEnglish
Pages (from-to)433-439
Number of pages7
JournalJournal of Colloid and Interface Science
Volume538
DOIs
Publication statusPublished - 7 Mar 2019

Keywords

  • Foam
  • Nanocellulose
  • Structure
  • Superabsorbent
  • TEMPO-mediated oxidation

Cite this

Mendoza, Llyza ; Hossain, Laila ; Downey, Emma ; Scales, Camilla ; Batchelor, Warren ; Garnier, Gil. / Carboxylated nanocellulose foams as superabsorbents. In: Journal of Colloid and Interface Science. 2019 ; Vol. 538. pp. 433-439.
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abstract = "Hypothesis: Carboxylated nanocellulose fibres formed into foam structures can demonstrate superabsorption capacity. Their performance can be engineered by changing process variables. Experiments: TEMPO-oxidised cellulose nanofibres of varying concentration and surface charge are produced from hardwood kraft pulp. Foams were prepared through a 2-step freezing and lyophilisation process. The absorption capacity of water and saline solution (0.9 wt{\%}) were measured as a function of time and related to the foam structure. Findings: The absorption capacity of nanocellulose foams can be manipulated from initial gel properties and processing conditions. Pore structure and distribution of nanocellulose foams are dictated by fibre content and charge density and freezing rate. The best performing foams are at 0.3–0.5 wt{\%}, with a carboxylate concentration of 1.2 mmol/g and frozen at −86 °C before freeze-drying, which can absorb 120 g H2O/g fibre. Fibre surface charge influences the absorption capacity of the foams by dictating the amount of participating carboxylate groups. Absorption capacity in saline (60 g/g) is lower than in deionised water (120 g/g); but is only slightly lower than that of a commercial polyacrylic acid (PAA) SAPs (80 g/g). Nanocellulose foams are attractive renewable alternatives for superabsorbent applications, contributing to a reduction of plastic microspheres.",
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Carboxylated nanocellulose foams as superabsorbents. / Mendoza, Llyza; Hossain, Laila; Downey, Emma; Scales, Camilla; Batchelor, Warren; Garnier, Gil.

In: Journal of Colloid and Interface Science, Vol. 538, 07.03.2019, p. 433-439.

Research output: Contribution to journalArticleResearchpeer-review

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