Capillary gas chromatography of metal-porphyrin complexes

Philip J. Marriott; J. Philip Gill; Geoffrey Eglinton

doi:10.1016/S0021-9673(00)84890-6

Capillary gas chromatography of metal-porphyrin complexes

Philip J. Marriott, J. Philip Gill, Geoffrey Eglinton

Research output: Contribution to journal › Article › Research › peer-review

28 Citations (Scopus)

Abstract

The first reported (conventional) gas chromatographic results for transition metal porphyrin complexes are presented. They may be the first metal complexes containing a closed macrocyclic ring to be gas chromatographed. Kovats retention indices are in the range of 5200-5600, necessitating the use of short capillary columns. For Aetioporphyrin I, complete separation of Cu, Ni, VO, Co, Pd and Pt complexes is possible, but with octaethylporphyrin the nickel and vanadyl complexes are incompletely resolved.

Original language	English
Pages (from-to)	395-401
Number of pages	7
Journal	Journal of Chromatography A
Volume	236
Issue number	2
DOIs	https://doi.org/10.1016/S0021-9673(00)84890-6
Publication status	Published - 19 Feb 1982
Externally published	Yes

Access to Document

10.1016/S0021-9673(00)84890-6

Cite this

@article{feaa561bd9ae43e7a883c36520fdfc3d,

title = "Capillary gas chromatography of metal-porphyrin complexes",

abstract = "The first reported (conventional) gas chromatographic results for transition metal porphyrin complexes are presented. They may be the first metal complexes containing a closed macrocyclic ring to be gas chromatographed. Kovats retention indices are in the range of 5200-5600, necessitating the use of short capillary columns. For Aetioporphyrin I, complete separation of Cu, Ni, VO, Co, Pd and Pt complexes is possible, but with octaethylporphyrin the nickel and vanadyl complexes are incompletely resolved.",

author = "Marriott, \{Philip J.\} and Gill, \{J. Philip\} and Geoffrey Eglinton",

year = "1982",

month = feb,

day = "19",

doi = "10.1016/S0021-9673(00)84890-6",

language = "English",

volume = "236",

pages = "395--401",

journal = "Journal of Chromatography A",

issn = "0021-9673",

publisher = "Elsevier BV",

number = "2",

}

TY - JOUR

T1 - Capillary gas chromatography of metal-porphyrin complexes

AU - Marriott, Philip J.

AU - Gill, J. Philip

AU - Eglinton, Geoffrey

PY - 1982/2/19

Y1 - 1982/2/19

N2 - The first reported (conventional) gas chromatographic results for transition metal porphyrin complexes are presented. They may be the first metal complexes containing a closed macrocyclic ring to be gas chromatographed. Kovats retention indices are in the range of 5200-5600, necessitating the use of short capillary columns. For Aetioporphyrin I, complete separation of Cu, Ni, VO, Co, Pd and Pt complexes is possible, but with octaethylporphyrin the nickel and vanadyl complexes are incompletely resolved.

AB - The first reported (conventional) gas chromatographic results for transition metal porphyrin complexes are presented. They may be the first metal complexes containing a closed macrocyclic ring to be gas chromatographed. Kovats retention indices are in the range of 5200-5600, necessitating the use of short capillary columns. For Aetioporphyrin I, complete separation of Cu, Ni, VO, Co, Pd and Pt complexes is possible, but with octaethylporphyrin the nickel and vanadyl complexes are incompletely resolved.

UR - https://www.scopus.com/pages/publications/49049131361

U2 - 10.1016/S0021-9673(00)84890-6

DO - 10.1016/S0021-9673(00)84890-6

M3 - Article

AN - SCOPUS:49049131361

SN - 0021-9673

VL - 236

SP - 395

EP - 401

JO - Journal of Chromatography A

JF - Journal of Chromatography A

IS - 2

ER -

Capillary gas chromatography of metal-porphyrin complexes

Abstract

Access to Document

Other files and links

Cite this