Abstract
The first reported (conventional) gas chromatographic results for transition metal porphyrin complexes are presented. They may be the first metal complexes containing a closed macrocyclic ring to be gas chromatographed. Kovats retention indices are in the range of 5200-5600, necessitating the use of short capillary columns. For Aetioporphyrin I, complete separation of Cu, Ni, VO, Co, Pd and Pt complexes is possible, but with octaethylporphyrin the nickel and vanadyl complexes are incompletely resolved.
| Original language | English |
|---|---|
| Pages (from-to) | 395-401 |
| Number of pages | 7 |
| Journal | Journal of Chromatography A |
| Volume | 236 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 19 Feb 1982 |
| Externally published | Yes |
Cite this
}
Capillary gas chromatography of metal-porphyrin complexes. / Marriott, Philip J.; Gill, J. Philip; Eglinton, Geoffrey.
In: Journal of Chromatography A, Vol. 236, No. 2, 19.02.1982, p. 395-401.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - Capillary gas chromatography of metal-porphyrin complexes
AU - Marriott, Philip J.
AU - Gill, J. Philip
AU - Eglinton, Geoffrey
PY - 1982/2/19
Y1 - 1982/2/19
N2 - The first reported (conventional) gas chromatographic results for transition metal porphyrin complexes are presented. They may be the first metal complexes containing a closed macrocyclic ring to be gas chromatographed. Kovats retention indices are in the range of 5200-5600, necessitating the use of short capillary columns. For Aetioporphyrin I, complete separation of Cu, Ni, VO, Co, Pd and Pt complexes is possible, but with octaethylporphyrin the nickel and vanadyl complexes are incompletely resolved.
AB - The first reported (conventional) gas chromatographic results for transition metal porphyrin complexes are presented. They may be the first metal complexes containing a closed macrocyclic ring to be gas chromatographed. Kovats retention indices are in the range of 5200-5600, necessitating the use of short capillary columns. For Aetioporphyrin I, complete separation of Cu, Ni, VO, Co, Pd and Pt complexes is possible, but with octaethylporphyrin the nickel and vanadyl complexes are incompletely resolved.
UR - http://www.scopus.com/inward/record.url?scp=49049131361&partnerID=8YFLogxK
U2 - 10.1016/S0021-9673(00)84890-6
DO - 10.1016/S0021-9673(00)84890-6
M3 - Article
VL - 236
SP - 395
EP - 401
JO - Journal of Chromatography A
JF - Journal of Chromatography A
SN - 0021-9673
IS - 2
ER -