Capillary gas chromatography of metal-porphyrin complexes

Philip J. Marriott; J. Philip Gill; Geoffrey Eglinton

doi:10.1016/S0021-9673(00)84890-6

Capillary gas chromatography of metal-porphyrin complexes

Philip J. Marriott, J. Philip Gill, Geoffrey Eglinton

Research output: Contribution to journal › Article › Research › peer-review

27 Citations (Scopus)

Abstract

The first reported (conventional) gas chromatographic results for transition metal porphyrin complexes are presented. They may be the first metal complexes containing a closed macrocyclic ring to be gas chromatographed. Kovats retention indices are in the range of 5200-5600, necessitating the use of short capillary columns. For Aetioporphyrin I, complete separation of Cu, Ni, VO, Co, Pd and Pt complexes is possible, but with octaethylporphyrin the nickel and vanadyl complexes are incompletely resolved.

Original language	English
Pages (from-to)	395-401
Number of pages	7
Journal	Journal of Chromatography A
Volume	236
Issue number	2
DOIs	https://doi.org/10.1016/S0021-9673(00)84890-6
Publication status	Published - 19 Feb 1982
Externally published	Yes

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10.1016/S0021-9673(00)84890-6

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Marriott, P. J., Gill, J. P., & Eglinton, G. (1982). Capillary gas chromatography of metal-porphyrin complexes. Journal of Chromatography A, 236(2), 395-401. https://doi.org/10.1016/S0021-9673(00)84890-6

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