Calixarene C8-imidazolium interplay as a design strategy for penetrating organic bi-layers

Irene Ling; Yatimah Alias; Alexandre N. Sobolev; Colin L. Raston

doi:10.1039/b913826a

Calixarene C₈-imidazolium interplay as a design strategy for penetrating organic bi-layers

Irene Ling, Yatimah Alias, Alexandre N. Sobolev, Colin L. Raston

Research output: Contribution to journal › Article › Research › peer-review

26 Citations (Scopus)

Abstract

1-Octyl-3-methylimidazolium (C₈-mim) cation forms multi-component bi-layers with p-sulfonatocalix[4]arene and phosphonium ions, and aquated lanthanide ions, with the imidazolium head group residing in the calixarene cavity and the terminus of the C₈ chain penetrating the adjacent hydrophobic bi-layer which is comprised of calixarenes and phosphonium ions, as part of a porous-like extended structure. Hirshfeld surface analyses reveal the nature of the interactions between the components.

Original language	English
Pages (from-to)	573-578
Number of pages	6
Journal	CrystEngComm
Volume	12
Issue number	2
DOIs	https://doi.org/10.1039/b913826a
Publication status	Published - 2010
Externally published	Yes

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AB - 1-Octyl-3-methylimidazolium (C8-mim) cation forms multi-component bi-layers with p-sulfonatocalix[4]arene and phosphonium ions, and aquated lanthanide ions, with the imidazolium head group residing in the calixarene cavity and the terminus of the C8 chain penetrating the adjacent hydrophobic bi-layer which is comprised of calixarenes and phosphonium ions, as part of a porous-like extended structure. Hirshfeld surface analyses reveal the nature of the interactions between the components.

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Calixarene C8-imidazolium interplay as a design strategy for penetrating organic bi-layers

Abstract

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Calixarene C₈-imidazolium interplay as a design strategy for penetrating organic bi-layers