Caging peroxide: anion-templated synthesis and characterization of a rare-earth cluster

William James Gee, Jonathan Gavin MacLellan, Craig Macdonald Forsyth, Boujemaa Moubaraki, Keith Spencer Murray, Philip Craig Andrews, Peter Courtney Junk

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16 Citations (Scopus)

Abstract

Sequestration of peroxide derived from molecular oxygen has resulted in the templated synthesis of a terbium picolinate cluster, isolated as a 2D sodiated network in the solid state. This first example of an air-stable rare-earth peroxide cluster represents key evidence for a peroxide-containing intermediate in rare-earth-cluster-catalyzed oxidation reactions. Luminescent and magnetic properties have also been investigated.
Original languageEnglish
Pages (from-to)8661 - 8663
Number of pages3
JournalInorganic Chemistry
Volume51
Issue number16
DOIs
Publication statusPublished - 2012

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