C-H activation of methyl arenes in the MnO2-mediated aroylation of N-chlorosulfoximines

Daniel Priebbenow, Carsten Bolm

Research output: Contribution to journalLetterOther

48 Citations (Scopus)

Abstract

An investigation into the reactivity profile of N-halogenated sulfoximines has led to the development of a new method for the synthesis of N-aroylated sulfoximines. This protocol involves the manganese oxide promoted C-H activation of methyl arenes to form an aroyl intermediate which then reacts readily with N-chlorosulfoximines to form a series of valuable aroyl sulfoximine derivatives in high yields
Original languageEnglish
Pages (from-to)1650 - 1652
Number of pages3
JournalOrganic Letters
Volume16
Issue number6
DOIs
Publication statusPublished - 2014
Externally publishedYes

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