C-H activation of ethers and alkanes by germylene-aryl halide complexes

Karla A. Miller; Jeffrey M. Bartolin; Rory M. O'Neill; Ryan D. Sweeder; Thomas M. Owens; Jeff W. Kampf; Mark M. Banaszak Holl; Norman J. Wells

doi:10.1021/ja0357285

C-H activation of ethers and alkanes by germylene-aryl halide complexes

Karla A. Miller
, Jeffrey M. Bartolin
, Rory M. O'Neill
, Ryan D. Sweeder
, Thomas M. Owens
, Jeff W. Kampf
, Mark M. Banaszak Holl
, Norman J. Wells

Research output: Contribution to journal › Article › Research › peer-review

62 Citations (Scopus)

Abstract

Regioselective, room-temperature C-H activation of alkanes and ethers by stable germylenes and aryl halides is reported. Germylenes, Ge[CH(SiMe₃)₂]₂ and Ge[N(SiMe₃)₂]₂, and aryl halides, PhI, PhBr, and PhCl, have been employed. High yields of C-H activation products can be obtained through the use of high-dilution techniques.

Original language	English
Pages (from-to)	8986-8987
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	30
DOIs	https://doi.org/10.1021/ja0357285
Publication status	Published - 30 Jul 2003
Externally published	Yes

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10.1021/ja0357285

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title = "C-H activation of ethers and alkanes by germylene-aryl halide complexes",

abstract = "Regioselective, room-temperature C-H activation of alkanes and ethers by stable germylenes and aryl halides is reported. Germylenes, Ge[CH(SiMe3)2]2 and Ge[N(SiMe3)2]2, and aryl halides, PhI, PhBr, and PhCl, have been employed. High yields of C-H activation products can be obtained through the use of high-dilution techniques.",

author = "Miller, \{Karla A.\} and Bartolin, \{Jeffrey M.\} and O'Neill, \{Rory M.\} and Sweeder, \{Ryan D.\} and Owens, \{Thomas M.\} and Kampf, \{Jeff W.\} and \{Banaszak Holl\}, \{Mark M.\} and Wells, \{Norman J.\}",

year = "2003",

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doi = "10.1021/ja0357285",

language = "English",

volume = "125",

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TY - JOUR

T1 - C-H activation of ethers and alkanes by germylene-aryl halide complexes

AU - Miller, Karla A.

AU - Bartolin, Jeffrey M.

AU - O'Neill, Rory M.

AU - Sweeder, Ryan D.

AU - Owens, Thomas M.

AU - Kampf, Jeff W.

AU - Banaszak Holl, Mark M.

AU - Wells, Norman J.

PY - 2003/7/30

Y1 - 2003/7/30

N2 - Regioselective, room-temperature C-H activation of alkanes and ethers by stable germylenes and aryl halides is reported. Germylenes, Ge[CH(SiMe3)2]2 and Ge[N(SiMe3)2]2, and aryl halides, PhI, PhBr, and PhCl, have been employed. High yields of C-H activation products can be obtained through the use of high-dilution techniques.

AB - Regioselective, room-temperature C-H activation of alkanes and ethers by stable germylenes and aryl halides is reported. Germylenes, Ge[CH(SiMe3)2]2 and Ge[N(SiMe3)2]2, and aryl halides, PhI, PhBr, and PhCl, have been employed. High yields of C-H activation products can be obtained through the use of high-dilution techniques.

UR - https://www.scopus.com/pages/publications/0041866687

U2 - 10.1021/ja0357285

DO - 10.1021/ja0357285

M3 - Article

AN - SCOPUS:0041866687

SN - 0002-7863

VL - 125

SP - 8986

EP - 8987

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 30

ER -

C-H activation of ethers and alkanes by germylene-aryl halide complexes

Abstract

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