C-C bond formation via C-H activation and C-N bond formation via oxidative amination catalyzed by palladium- polyoxometalate nanomaterials using dioxygen as the terminal oxidant

Leng Chng, Jie Zhang, Jinhua Yang, Makhlouf Amoura, Jackie Ying

Research output: Contribution to journalArticleResearchpeer-review

55 Citations (Scopus)

Abstract

An efficient heterogeneous palladiumpolyoxometalate catalyst with the formula Pd- H6PV3Mo9O40/C has been successfully developed for carbon-carbon (C C) bond formation via carbon-hydrogen (C H) activation and carbon-nitrogen (C N) bond formation via oxidative amination using oxygen as the terminal oxidant. The coupling processes are simple, and use relatively mild conditions to form the desired products. In addition, less waste is generated as no additional reagents such as organic/ inorganic oxidants are required, and water is the only by-product generated.
Original languageEnglish
Pages (from-to)2988 - 2998
Number of pages11
JournalAdvanced Synthesis and Catalysis
Volume353
Issue number16
DOIs
Publication statusPublished - 2011
Externally publishedYes

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