TY - JOUR
T1 - Bulky cations and four different polyiodide anions in [Lu(Db18c6)(H 2O)3(thf)6]4(I3) 2(I5)6(I8)(I12)
AU - Walbaum, Christine
AU - Pantenburg, Ingo
AU - Junk, Peter Courtney
AU - Deacon, Glen Berenger
AU - Meyer, Gerd
PY - 2010
Y1 - 2010
N2 - Black single crystals of [Lu(Db18c6)(H2O)3(thf)6]4(I3)2(I5)6(I8)(I12) were obtained from lutetium, I2 and Db18c6 (dibenzo-18-crown-6) in THF solution. In the bulky cation, Lu3+ is surrounded by nine oxygen atoms, six of Db18c6 and three of water molecules to which two THF molecules are attached each. Meanwhile, four polyiodide anions, (I3)a??, (I5)a??, (I8)2a?? and (I12)2a??, in a 2:6:1:1 ratio form a three-dimensional network and leave space for the bulky cations.
AB - Black single crystals of [Lu(Db18c6)(H2O)3(thf)6]4(I3)2(I5)6(I8)(I12) were obtained from lutetium, I2 and Db18c6 (dibenzo-18-crown-6) in THF solution. In the bulky cation, Lu3+ is surrounded by nine oxygen atoms, six of Db18c6 and three of water molecules to which two THF molecules are attached each. Meanwhile, four polyiodide anions, (I3)a??, (I5)a??, (I8)2a?? and (I12)2a??, in a 2:6:1:1 ratio form a three-dimensional network and leave space for the bulky cations.
UR - http://onlinelibrary.wiley.com.ezproxy.lib.monash.edu.au/doi/10.1002/zaac.201000112/pdf
U2 - 10.1002/zaac.201000112
DO - 10.1002/zaac.201000112
M3 - Article
SN - 1521-3749
VL - 636
SP - 1444
EP - 1446
JO - Zeitschrift fuer Anorganische und Allgemeine Chemie
JF - Zeitschrift fuer Anorganische und Allgemeine Chemie
IS - 8
ER -