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Building a Lewis Acidic Phosphorus

  • Madelyn Qin Yi Tay
  • , Yunpeng Lu
  • , Rakesh Ganguly
  • , Gilles Frison
  • , Louis Ricard
  • , Dragoslav Vidović
  • , Duncan Carmichael

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Using the σ- and π-donating properties of carbodiphosphorane ligands, we recently synthesized a phosphorus (III)-containing dication. It is observed to undergo interesting reactivity with PMe3, H2O, and MeOH.

Original languageEnglish
Pages (from-to)785-788
Number of pages4
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume190
Issue number5-6
DOIs
Publication statusPublished - 3 Jun 2015
Externally publishedYes

Keywords

  • carbodiphosphoranes
  • dication
  • Phosphenium
  • two-coordinate

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