Building a Lewis Acidic Phosphorus

Madelyn Qin Yi Tay, Yunpeng Lu, Rakesh Ganguly, Gilles Frison, Louis Ricard, Dragoslav Vidović, Duncan Carmichael

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6 Citations (Scopus)

Abstract

Using the σ- and π-donating properties of carbodiphosphorane ligands, we recently synthesized a phosphorus (III)-containing dication. It is observed to undergo interesting reactivity with PMe3, H2O, and MeOH.

Original languageEnglish
Pages (from-to)785-788
Number of pages4
JournalPhosphorus, Sulfur and Silicon and the Related Elements
Volume190
Issue number5-6
DOIs
Publication statusPublished - 3 Jun 2015
Externally publishedYes

Keywords

  • carbodiphosphoranes
  • dication
  • Phosphenium
  • two-coordinate

Cite this

Tay, M. Q. Y., Lu, Y., Ganguly, R., Frison, G., Ricard, L., Vidović, D., & Carmichael, D. (2015). Building a Lewis Acidic Phosphorus. Phosphorus, Sulfur and Silicon and the Related Elements, 190(5-6), 785-788. https://doi.org/10.1080/10426507.2014.980413