Borenium ionic liquids as catalysts for Diels-Alder reaction: Tuneable Lewis superacids for catalytic applications

K. Matuszek; S. Coffie; A. Chrobok; M. Swadźba-Kwaśny

doi:10.1039/c7cy00106a

Borenium ionic liquids as catalysts for Diels-Alder reaction: Tuneable Lewis superacids for catalytic applications

K. Matuszek, S. Coffie, A. Chrobok, M. Swadźba-Kwaśny

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

24 Citations (Scopus)

Abstract

Ionic liquids based on the tricoordinate borenium cation were used for the first time as Lewis acid catalysts for a model Diels-Alder reaction. The conversion of the dienophile was successfully correlated with the Gutmann acceptor number values of the ionic liquids. Borenium ionic liquids exceeded the performance of catalysts reported in the literature.

Original language	English
Pages (from-to)	1045-1049
Number of pages	5
Journal	Catalysis Science & Technology
Volume	7
Issue number	5
DOIs	https://doi.org/10.1039/c7cy00106a
Publication status	Published - 1 Jan 2017

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abstract = "Ionic liquids based on the tricoordinate borenium cation were used for the first time as Lewis acid catalysts for a model Diels-Alder reaction. The conversion of the dienophile was successfully correlated with the Gutmann acceptor number values of the ionic liquids. Borenium ionic liquids exceeded the performance of catalysts reported in the literature.",

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AB - Ionic liquids based on the tricoordinate borenium cation were used for the first time as Lewis acid catalysts for a model Diels-Alder reaction. The conversion of the dienophile was successfully correlated with the Gutmann acceptor number values of the ionic liquids. Borenium ionic liquids exceeded the performance of catalysts reported in the literature.

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Borenium ionic liquids as catalysts for Diels-Alder reaction: Tuneable Lewis superacids for catalytic applications

Abstract

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