利用嵌段共聚物及无机盐合成高质量的立方相、大孔径介孔氧化硅球

Translated title of the contribution: Block copolymer synthesis of high-quality cubic, large pore mesoporous millimeter spheres in the presence of inorganic salts

Cheng Zhong Yu, Jie Fan, Dong Yuan Zhao

Research output: Contribution to journalArticleResearchpeer-review

13 Citations (Scopus)

Abstract

Highly ordered cubic mesoporous silica SBA-16 with millimeter spherical morphology (2-4 mm in diameter) has been synthesized using triblock copolymer as templates in the presence of inorganic salts. The use of inorganic salts greatly improves the quality of the resulted mesostructure by increasing the self-assemble ability of organic species and results in the formation of millimeter spheres by enhancing the interaction at the inorganic/organic interface. The calcined millimeter SBA-16 spheres have a surface area of 750 m2/g, a pore volume of 0.52 cm3/g, and a large pore size of 7.8 nm. These millimeter spheres may be readily used in the separation of large molecules.

Translated title of the contributionBlock copolymer synthesis of high-quality cubic, large pore mesoporous millimeter spheres in the presence of inorganic salts
Original languageChinese
Pages (from-to)1357-1360
Number of pages4
JournalActa Chimica Sinica
Volume60
Issue number8
Publication statusPublished - 1 Dec 2002
Externally publishedYes

Keywords

  • Block copolymer
  • Mesoporous
  • Morphology
  • Synthesis

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