Bis(pentafluorophenyl)(N,N,N',N'-tetramethylethylenediamine)platinum(II)

Glen B. Deacon; Keith T. Nelson; Edward R T Tiekink

doi:10.1107/S0108270191002743

Bis(pentafluorophenyl)(N,N,N',N'-tetramethylethylenediamine)platinum(II)

Glen B. Deacon
, Keith T. Nelson
, Edward R T Tiekink

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

9 Citations (Scopus)

Abstract

[Pt(C₆F₅)₂(tmen)], C₁₈H ₁₆F₁₀N₂Pt, M_r = 645·5, monoclinic, C2/c, a = 19·526 (6), b = 8·554 (1), c = 13·282 (2) Å, β = 113·43 (2)°, V = 2036 (3) Å³, Z = 4, D_x = 2·106 g cm^-3, λ(Mo Kα) = 0·7107 Å, μ = 70·21 cm^-1 F(000) = 1224, T = 293(1)K, R = 0·040 for 1906 observed reflections. The Pt atom in the title compound, which lies on a crystallographic twofold axis, exists in a distorted square planar geometry comprised of a chelating tetramethylethylenediamine (tmen) ligand [Pt - N 2·141(5)Å] and two pentafluorophenyl groups [Pt - C 2·006 (6)Å] which make an angle of 87·1° with the square plane.

Original language	English
Pages (from-to)	1819-1821
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	47
Issue number	9
DOIs	https://doi.org/10.1107/S0108270191002743
Publication status	Published - 1991

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@article{56b744715d7c4d53a9374fe334ca955b,

title = "Bis(pentafluorophenyl)(N,N,N',N'-tetramethylethylenediamine)platinum(II)",

abstract = "[Pt(C6F5)2(tmen)], C18H 16F10N2Pt, Mr = 645·5, monoclinic, C2/c, a = 19·526 (6), b = 8·554 (1), c = 13·282 (2) {\AA}, β = 113·43 (2)°, V = 2036 (3) {\AA}3, Z = 4, Dx = 2·106 g cm-3, λ(Mo Kα) = 0·7107 {\AA}, μ = 70·21 cm-1 F(000) = 1224, T = 293(1)K, R = 0·040 for 1906 observed reflections. The Pt atom in the title compound, which lies on a crystallographic twofold axis, exists in a distorted square planar geometry comprised of a chelating tetramethylethylenediamine (tmen) ligand [Pt - N 2·141(5){\AA}] and two pentafluorophenyl groups [Pt - C 2·006 (6){\AA}] which make an angle of 87·1° with the square plane.",

author = "Deacon, \{Glen B.\} and Nelson, \{Keith T.\} and Tiekink, \{Edward R T\}",

year = "1991",

doi = "10.1107/S0108270191002743",

language = "English",

volume = "47",

pages = "1819--1821",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography (IUCr)",

number = "9",

}

TY - JOUR

T1 - Bis(pentafluorophenyl)(N,N,N',N'-tetramethylethylenediamine)platinum(II)

AU - Deacon, Glen B.

AU - Nelson, Keith T.

AU - Tiekink, Edward R T

PY - 1991

Y1 - 1991

N2 - [Pt(C6F5)2(tmen)], C18H 16F10N2Pt, Mr = 645·5, monoclinic, C2/c, a = 19·526 (6), b = 8·554 (1), c = 13·282 (2) Å, β = 113·43 (2)°, V = 2036 (3) Å3, Z = 4, Dx = 2·106 g cm-3, λ(Mo Kα) = 0·7107 Å, μ = 70·21 cm-1 F(000) = 1224, T = 293(1)K, R = 0·040 for 1906 observed reflections. The Pt atom in the title compound, which lies on a crystallographic twofold axis, exists in a distorted square planar geometry comprised of a chelating tetramethylethylenediamine (tmen) ligand [Pt - N 2·141(5)Å] and two pentafluorophenyl groups [Pt - C 2·006 (6)Å] which make an angle of 87·1° with the square plane.

AB - [Pt(C6F5)2(tmen)], C18H 16F10N2Pt, Mr = 645·5, monoclinic, C2/c, a = 19·526 (6), b = 8·554 (1), c = 13·282 (2) Å, β = 113·43 (2)°, V = 2036 (3) Å3, Z = 4, Dx = 2·106 g cm-3, λ(Mo Kα) = 0·7107 Å, μ = 70·21 cm-1 F(000) = 1224, T = 293(1)K, R = 0·040 for 1906 observed reflections. The Pt atom in the title compound, which lies on a crystallographic twofold axis, exists in a distorted square planar geometry comprised of a chelating tetramethylethylenediamine (tmen) ligand [Pt - N 2·141(5)Å] and two pentafluorophenyl groups [Pt - C 2·006 (6)Å] which make an angle of 87·1° with the square plane.

UR - https://www.scopus.com/pages/publications/4243997378

U2 - 10.1107/S0108270191002743

DO - 10.1107/S0108270191002743

M3 - Article

AN - SCOPUS:4243997378

SN - 0108-2701

VL - 47

SP - 1819

EP - 1821

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 9

ER -

Bis(pentafluorophenyl)(N,N,N',N'-tetramethylethylenediamine)platinum(II)

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