Bis(pentafluorophenyl)(N,N,N',N'-tetramethylethylenediamine)platinum(II)

Glen B. Deacon, Keith T. Nelson, Edward R T Tiekink

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9 Citations (Scopus)

Abstract

[Pt(C6F5)2(tmen)], C18H 16F10N2Pt, Mr = 645·5, monoclinic, C2/c, a = 19·526 (6), b = 8·554 (1), c = 13·282 (2) Å, β = 113·43 (2)°, V = 2036 (3) Å3, Z = 4, Dx = 2·106 g cm-3, λ(Mo Kα) = 0·7107 Å, μ = 70·21 cm-1 F(000) = 1224, T = 293(1)K, R = 0·040 for 1906 observed reflections. The Pt atom in the title compound, which lies on a crystallographic twofold axis, exists in a distorted square planar geometry comprised of a chelating tetramethylethylenediamine (tmen) ligand [Pt - N 2·141(5)Å] and two pentafluorophenyl groups [Pt - C 2·006 (6)Å] which make an angle of 87·1° with the square plane.

Original languageEnglish
Pages (from-to)1819-1821
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume47
Issue number9
DOIs
Publication statusPublished - 1991

Cite this

@article{56b744715d7c4d53a9374fe334ca955b,
title = "Bis(pentafluorophenyl)(N,N,N',N'-tetramethylethylenediamine)platinum(II)",
abstract = "[Pt(C6F5)2(tmen)], C18H 16F10N2Pt, Mr = 645·5, monoclinic, C2/c, a = 19·526 (6), b = 8·554 (1), c = 13·282 (2) {\AA}, β = 113·43 (2)°, V = 2036 (3) {\AA}3, Z = 4, Dx = 2·106 g cm-3, λ(Mo Kα) = 0·7107 {\AA}, μ = 70·21 cm-1 F(000) = 1224, T = 293(1)K, R = 0·040 for 1906 observed reflections. The Pt atom in the title compound, which lies on a crystallographic twofold axis, exists in a distorted square planar geometry comprised of a chelating tetramethylethylenediamine (tmen) ligand [Pt - N 2·141(5){\AA}] and two pentafluorophenyl groups [Pt - C 2·006 (6){\AA}] which make an angle of 87·1° with the square plane.",
author = "Deacon, {Glen B.} and Nelson, {Keith T.} and Tiekink, {Edward R T}",
year = "1991",
doi = "10.1107/S0108270191002743",
language = "English",
volume = "47",
pages = "1819--1821",
journal = "Acta Crystallographica Section C: Structural Chemistry",
issn = "2053-2296",
publisher = "International Union of Crystallography",
number = "9",

}

Bis(pentafluorophenyl)(N,N,N',N'-tetramethylethylenediamine)platinum(II). / Deacon, Glen B.; Nelson, Keith T.; Tiekink, Edward R T.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 47, No. 9, 1991, p. 1819-1821.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Bis(pentafluorophenyl)(N,N,N',N'-tetramethylethylenediamine)platinum(II)

AU - Deacon, Glen B.

AU - Nelson, Keith T.

AU - Tiekink, Edward R T

PY - 1991

Y1 - 1991

N2 - [Pt(C6F5)2(tmen)], C18H 16F10N2Pt, Mr = 645·5, monoclinic, C2/c, a = 19·526 (6), b = 8·554 (1), c = 13·282 (2) Å, β = 113·43 (2)°, V = 2036 (3) Å3, Z = 4, Dx = 2·106 g cm-3, λ(Mo Kα) = 0·7107 Å, μ = 70·21 cm-1 F(000) = 1224, T = 293(1)K, R = 0·040 for 1906 observed reflections. The Pt atom in the title compound, which lies on a crystallographic twofold axis, exists in a distorted square planar geometry comprised of a chelating tetramethylethylenediamine (tmen) ligand [Pt - N 2·141(5)Å] and two pentafluorophenyl groups [Pt - C 2·006 (6)Å] which make an angle of 87·1° with the square plane.

AB - [Pt(C6F5)2(tmen)], C18H 16F10N2Pt, Mr = 645·5, monoclinic, C2/c, a = 19·526 (6), b = 8·554 (1), c = 13·282 (2) Å, β = 113·43 (2)°, V = 2036 (3) Å3, Z = 4, Dx = 2·106 g cm-3, λ(Mo Kα) = 0·7107 Å, μ = 70·21 cm-1 F(000) = 1224, T = 293(1)K, R = 0·040 for 1906 observed reflections. The Pt atom in the title compound, which lies on a crystallographic twofold axis, exists in a distorted square planar geometry comprised of a chelating tetramethylethylenediamine (tmen) ligand [Pt - N 2·141(5)Å] and two pentafluorophenyl groups [Pt - C 2·006 (6)Å] which make an angle of 87·1° with the square plane.

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U2 - 10.1107/S0108270191002743

DO - 10.1107/S0108270191002743

M3 - Article

VL - 47

SP - 1819

EP - 1821

JO - Acta Crystallographica Section C: Structural Chemistry

JF - Acta Crystallographica Section C: Structural Chemistry

SN - 2053-2296

IS - 9

ER -