Abstract
[Pt(C6F5)2(tmen)], C18H 16F10N2Pt, Mr = 645·5, monoclinic, C2/c, a = 19·526 (6), b = 8·554 (1), c = 13·282 (2) Å, β = 113·43 (2)°, V = 2036 (3) Å3, Z = 4, Dx = 2·106 g cm-3, λ(Mo Kα) = 0·7107 Å, μ = 70·21 cm-1 F(000) = 1224, T = 293(1)K, R = 0·040 for 1906 observed reflections. The Pt atom in the title compound, which lies on a crystallographic twofold axis, exists in a distorted square planar geometry comprised of a chelating tetramethylethylenediamine (tmen) ligand [Pt - N 2·141(5)Å] and two pentafluorophenyl groups [Pt - C 2·006 (6)Å] which make an angle of 87·1° with the square plane.
| Original language | English |
|---|---|
| Pages (from-to) | 1819-1821 |
| Number of pages | 3 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 47 |
| Issue number | 9 |
| DOIs | |
| Publication status | Published - 1991 |
Cite this
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Bis(pentafluorophenyl)(N,N,N',N'-tetramethylethylenediamine)platinum(II). / Deacon, Glen B.; Nelson, Keith T.; Tiekink, Edward R T.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 47, No. 9, 1991, p. 1819-1821.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - Bis(pentafluorophenyl)(N,N,N',N'-tetramethylethylenediamine)platinum(II)
AU - Deacon, Glen B.
AU - Nelson, Keith T.
AU - Tiekink, Edward R T
PY - 1991
Y1 - 1991
N2 - [Pt(C6F5)2(tmen)], C18H 16F10N2Pt, Mr = 645·5, monoclinic, C2/c, a = 19·526 (6), b = 8·554 (1), c = 13·282 (2) Å, β = 113·43 (2)°, V = 2036 (3) Å3, Z = 4, Dx = 2·106 g cm-3, λ(Mo Kα) = 0·7107 Å, μ = 70·21 cm-1 F(000) = 1224, T = 293(1)K, R = 0·040 for 1906 observed reflections. The Pt atom in the title compound, which lies on a crystallographic twofold axis, exists in a distorted square planar geometry comprised of a chelating tetramethylethylenediamine (tmen) ligand [Pt - N 2·141(5)Å] and two pentafluorophenyl groups [Pt - C 2·006 (6)Å] which make an angle of 87·1° with the square plane.
AB - [Pt(C6F5)2(tmen)], C18H 16F10N2Pt, Mr = 645·5, monoclinic, C2/c, a = 19·526 (6), b = 8·554 (1), c = 13·282 (2) Å, β = 113·43 (2)°, V = 2036 (3) Å3, Z = 4, Dx = 2·106 g cm-3, λ(Mo Kα) = 0·7107 Å, μ = 70·21 cm-1 F(000) = 1224, T = 293(1)K, R = 0·040 for 1906 observed reflections. The Pt atom in the title compound, which lies on a crystallographic twofold axis, exists in a distorted square planar geometry comprised of a chelating tetramethylethylenediamine (tmen) ligand [Pt - N 2·141(5)Å] and two pentafluorophenyl groups [Pt - C 2·006 (6)Å] which make an angle of 87·1° with the square plane.
UR - http://www.scopus.com/inward/record.url?scp=4243997378&partnerID=8YFLogxK
U2 - 10.1107/S0108270191002743
DO - 10.1107/S0108270191002743
M3 - Article
VL - 47
SP - 1819
EP - 1821
JO - Acta Crystallographica Section C: Structural Chemistry
JF - Acta Crystallographica Section C: Structural Chemistry
SN - 2053-2296
IS - 9
ER -