Biological synthesis of triangular gold nanoprisms

S. Shiv Shankar, Akhilesh Rai, Balaprasad Ankamwar, Amit Singh, Absar Ahmad, Murali Sastry

Research output: Contribution to journalArticleResearchpeer-review

1327 Citations (Scopus)

Abstract

The optoelectronic and physicochemical properties of nanoscale matter are a strong function of particle size. Nanoparticle shape also contributes significantly to modulating their electronic properties. Several shapes ranging from rods to wires to plates to teardrop structures may be obtained by chemical methods; triangular nanoparticles have been synthesized by using a seeded growth process. Here, we report the discovery that the extract from the lemongrass plant, when reacted with aqueous chloroaurate ions, yields a high percentage of thin, flat, single-crystalline gold nanotriangles. The nanotriangles seem to grow by a process involving rapid reduction, assembly and room-temperature sintering of 'liquid-like' spherical gold nanoparticles. The anisotropy in nanoparticle shape results in large near-infrared absorption by the particles, and highly anisotropic electron transport in films of the nanotriangles.

Original languageEnglish
Pages (from-to)482-488
Number of pages7
JournalNature Materials
Volume3
Issue number7
DOIs
Publication statusPublished - Jul 2004
Externally publishedYes

Cite this