Biodiesel production using calcium-based catalyst from venus shell

modeling of startup production in an industrial reactor

Yong Sun, Jingping Zhang, Zhi Sun, Lian Zhang

Research output: Contribution to journalArticleResearchpeer-review

Abstract

Calcium oxide-based catalyst was produced from Venus shell by fast fluidized bed calcination for biodiesel synthesis. The kinetics of biodiesel synthesis was found to be a pseudo-first-order reaction at the experimental conditions. The obtained kinetic parameters were used for modeling the startup operation of biodiesel production in an industrial continuous stirred tank reactor (CSTR). The model was found to agree well with the reagent concentration and temperature profiles in a real production practice during biodiesel production. The variations of initial temperature, initial reagent concentration in the reactor was investigated. It was found that the reagent concentration and temperature oscillated around the final steady state. From safety operation perspective, the first 4 h were found to be the most unsteady period during continuous production. The initial concentration of waste fry oil (WFO) was also found to be critical to the safe operation of CSTR. A violation of the settings for safe operation of CSTR will be triggered once the initial concentration of WFO in CSTR reaches 500 mol m −3 .

Original languageEnglish
Article numbere13053
Number of pages9
JournalEnvironmental Progress and Sustainable Energy
Volume38
Issue number3
DOIs
Publication statusPublished - 1 May 2019

Keywords

  • biodiesel
  • catalyst
  • industrial production
  • process safety

Cite this

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title = "Biodiesel production using calcium-based catalyst from venus shell: modeling of startup production in an industrial reactor",
abstract = "Calcium oxide-based catalyst was produced from Venus shell by fast fluidized bed calcination for biodiesel synthesis. The kinetics of biodiesel synthesis was found to be a pseudo-first-order reaction at the experimental conditions. The obtained kinetic parameters were used for modeling the startup operation of biodiesel production in an industrial continuous stirred tank reactor (CSTR). The model was found to agree well with the reagent concentration and temperature profiles in a real production practice during biodiesel production. The variations of initial temperature, initial reagent concentration in the reactor was investigated. It was found that the reagent concentration and temperature oscillated around the final steady state. From safety operation perspective, the first 4 h were found to be the most unsteady period during continuous production. The initial concentration of waste fry oil (WFO) was also found to be critical to the safe operation of CSTR. A violation of the settings for safe operation of CSTR will be triggered once the initial concentration of WFO in CSTR reaches 500 mol m −3 .",
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Biodiesel production using calcium-based catalyst from venus shell : modeling of startup production in an industrial reactor. / Sun, Yong; Zhang, Jingping; Sun, Zhi; Zhang, Lian.

In: Environmental Progress and Sustainable Energy, Vol. 38, No. 3, e13053, 01.05.2019.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Biodiesel production using calcium-based catalyst from venus shell

T2 - modeling of startup production in an industrial reactor

AU - Sun, Yong

AU - Zhang, Jingping

AU - Sun, Zhi

AU - Zhang, Lian

PY - 2019/5/1

Y1 - 2019/5/1

N2 - Calcium oxide-based catalyst was produced from Venus shell by fast fluidized bed calcination for biodiesel synthesis. The kinetics of biodiesel synthesis was found to be a pseudo-first-order reaction at the experimental conditions. The obtained kinetic parameters were used for modeling the startup operation of biodiesel production in an industrial continuous stirred tank reactor (CSTR). The model was found to agree well with the reagent concentration and temperature profiles in a real production practice during biodiesel production. The variations of initial temperature, initial reagent concentration in the reactor was investigated. It was found that the reagent concentration and temperature oscillated around the final steady state. From safety operation perspective, the first 4 h were found to be the most unsteady period during continuous production. The initial concentration of waste fry oil (WFO) was also found to be critical to the safe operation of CSTR. A violation of the settings for safe operation of CSTR will be triggered once the initial concentration of WFO in CSTR reaches 500 mol m −3 .

AB - Calcium oxide-based catalyst was produced from Venus shell by fast fluidized bed calcination for biodiesel synthesis. The kinetics of biodiesel synthesis was found to be a pseudo-first-order reaction at the experimental conditions. The obtained kinetic parameters were used for modeling the startup operation of biodiesel production in an industrial continuous stirred tank reactor (CSTR). The model was found to agree well with the reagent concentration and temperature profiles in a real production practice during biodiesel production. The variations of initial temperature, initial reagent concentration in the reactor was investigated. It was found that the reagent concentration and temperature oscillated around the final steady state. From safety operation perspective, the first 4 h were found to be the most unsteady period during continuous production. The initial concentration of waste fry oil (WFO) was also found to be critical to the safe operation of CSTR. A violation of the settings for safe operation of CSTR will be triggered once the initial concentration of WFO in CSTR reaches 500 mol m −3 .

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KW - industrial production

KW - process safety

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