Bio-resourced eugenol derived phthalonitrile resin for high temperature composite

Yi Ning; Dian-sen Li; Ming-cun Wang; Lei Jiang

doi:10.1002/app.50721

Bio-resourced eugenol derived phthalonitrile resin for high temperature composite

Yi Ning, Dian-sen Li, Ming-cun Wang, Lei Jiang

Research output: Contribution to journal › Article › Research › peer-review

28 Citations (Scopus)

Abstract

Eugenol (EG) is an abundant renewable compound that has been widely used in the synthesis of bio-based thermosetting resin, but there are few reports on the phthalonitrile (PN) resin derived from EG. In this study, a new kind of bio-based PN resin (MEG-PN) derived from EG derivative was successfully synthesized. PN is a traditional class of high-performance thermosets with poor processability for its ultra-high melting point and curing temperature. The MEG-PN resin possesses excellent processability: its melting temperature is much lower (77°C), and it can be cured at a moderate temperature (281°C) in the absence of curing agents. The cured MEG-PN resin exhibited great heat resistance according to its 5% weight loss temperature at 448°C and its char yield percentage as high as 75.6% at 800°C under nitrogen. The properties of the carbon-fiber reinforced MEG-PN composite were comparable to those of petroleum-based PN resins: the glass transition temperature was around 397°C; the flexural strength and modulus were as high as 756 MPa and 119 GPa, respectively. Overall, a bio-based PN thermoset with great comprehensive performance was synthesized possessing the potential in the application of advanced composite.

Original language	English
Article number	50721
Number of pages	12
Journal	Journal of Applied Polymer Science
Volume	138
Issue number	30
DOIs	https://doi.org/10.1002/app.50721
Publication status	Published - 10 Aug 2021
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

applications
biopolymers and renewable polymers
rheology

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10.1002/app.50721

Cite this

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title = "Bio-resourced eugenol derived phthalonitrile resin for high temperature composite",

abstract = "Eugenol (EG) is an abundant renewable compound that has been widely used in the synthesis of bio-based thermosetting resin, but there are few reports on the phthalonitrile (PN) resin derived from EG. In this study, a new kind of bio-based PN resin (MEG-PN) derived from EG derivative was successfully synthesized. PN is a traditional class of high-performance thermosets with poor processability for its ultra-high melting point and curing temperature. The MEG-PN resin possesses excellent processability: its melting temperature is much lower (77°C), and it can be cured at a moderate temperature (281°C) in the absence of curing agents. The cured MEG-PN resin exhibited great heat resistance according to its 5\% weight loss temperature at 448°C and its char yield percentage as high as 75.6\% at 800°C under nitrogen. The properties of the carbon-fiber reinforced MEG-PN composite were comparable to those of petroleum-based PN resins: the glass transition temperature was around 397°C; the flexural strength and modulus were as high as 756 MPa and 119 GPa, respectively. Overall, a bio-based PN thermoset with great comprehensive performance was synthesized possessing the potential in the application of advanced composite.",

keywords = "applications, biopolymers and renewable polymers, rheology",

author = "Yi Ning and Dian-sen Li and Ming-cun Wang and Lei Jiang",

note = "Funding Information: The authors acknowledge the financial supports from by Excellent Young Scientist Foundation of NSFC (No.11522216); National Natural Science Foundation of China (No.11872087). Beijing Municipal Natural Science Foundation (No. 2182033); Aeronautical Science Foundation of China (No. 2016ZF51054); the 111 Project (No. B14009); Project of the Science and Technology Commission of Military Commission (No. 17-163-12-ZT-004-002-01); Foundation of Shock and Vibration of Engineering Materials and Structures Key Laboratory of Sichuan Province (No.18kfgk01); Foundation of State Key Laboratory for Strength and Vibration of Mechanical Structures (No. SV2019-KF-32); Foundation of State Key Laboratory of Explosion Science and Technology of Beijing Institute of Technology (No. KFJJ21-06M). Publisher Copyright: {\textcopyright} 2021 Wiley Periodicals LLC.",

year = "2021",

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doi = "10.1002/app.50721",

language = "English",

volume = "138",

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T1 - Bio-resourced eugenol derived phthalonitrile resin for high temperature composite

AU - Ning, Yi

AU - Li, Dian-sen

AU - Wang, Ming-cun

AU - Jiang, Lei

N1 - Funding Information: The authors acknowledge the financial supports from by Excellent Young Scientist Foundation of NSFC (No.11522216); National Natural Science Foundation of China (No.11872087). Beijing Municipal Natural Science Foundation (No. 2182033); Aeronautical Science Foundation of China (No. 2016ZF51054); the 111 Project (No. B14009); Project of the Science and Technology Commission of Military Commission (No. 17-163-12-ZT-004-002-01); Foundation of Shock and Vibration of Engineering Materials and Structures Key Laboratory of Sichuan Province (No.18kfgk01); Foundation of State Key Laboratory for Strength and Vibration of Mechanical Structures (No. SV2019-KF-32); Foundation of State Key Laboratory of Explosion Science and Technology of Beijing Institute of Technology (No. KFJJ21-06M). Publisher Copyright: © 2021 Wiley Periodicals LLC.

PY - 2021/8/10

Y1 - 2021/8/10

N2 - Eugenol (EG) is an abundant renewable compound that has been widely used in the synthesis of bio-based thermosetting resin, but there are few reports on the phthalonitrile (PN) resin derived from EG. In this study, a new kind of bio-based PN resin (MEG-PN) derived from EG derivative was successfully synthesized. PN is a traditional class of high-performance thermosets with poor processability for its ultra-high melting point and curing temperature. The MEG-PN resin possesses excellent processability: its melting temperature is much lower (77°C), and it can be cured at a moderate temperature (281°C) in the absence of curing agents. The cured MEG-PN resin exhibited great heat resistance according to its 5% weight loss temperature at 448°C and its char yield percentage as high as 75.6% at 800°C under nitrogen. The properties of the carbon-fiber reinforced MEG-PN composite were comparable to those of petroleum-based PN resins: the glass transition temperature was around 397°C; the flexural strength and modulus were as high as 756 MPa and 119 GPa, respectively. Overall, a bio-based PN thermoset with great comprehensive performance was synthesized possessing the potential in the application of advanced composite.

AB - Eugenol (EG) is an abundant renewable compound that has been widely used in the synthesis of bio-based thermosetting resin, but there are few reports on the phthalonitrile (PN) resin derived from EG. In this study, a new kind of bio-based PN resin (MEG-PN) derived from EG derivative was successfully synthesized. PN is a traditional class of high-performance thermosets with poor processability for its ultra-high melting point and curing temperature. The MEG-PN resin possesses excellent processability: its melting temperature is much lower (77°C), and it can be cured at a moderate temperature (281°C) in the absence of curing agents. The cured MEG-PN resin exhibited great heat resistance according to its 5% weight loss temperature at 448°C and its char yield percentage as high as 75.6% at 800°C under nitrogen. The properties of the carbon-fiber reinforced MEG-PN composite were comparable to those of petroleum-based PN resins: the glass transition temperature was around 397°C; the flexural strength and modulus were as high as 756 MPa and 119 GPa, respectively. Overall, a bio-based PN thermoset with great comprehensive performance was synthesized possessing the potential in the application of advanced composite.

KW - applications

KW - biopolymers and renewable polymers

KW - rheology

UR - https://www.scopus.com/pages/publications/85102472052

U2 - 10.1002/app.50721

DO - 10.1002/app.50721

M3 - Article

AN - SCOPUS:85102472052

SN - 0021-8995

VL - 138

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 30

M1 - 50721

ER -

Bio-resourced eugenol derived phthalonitrile resin for high temperature composite

Abstract

UN SDGs

Keywords

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