Asymmetric synthesis of (+)- and (-)-pauciflorol F: Confirmation of absolute stereochemistry

Daniel Jarrah Kerr, Michael Miletic, Narasimhulu Manchala, Jonathan White, Bernard Luke Flynn

Research output: Contribution to journalArticleResearchpeer-review

43 Citations (Scopus)

Abstract

An efficient, formal enantioselective synthesis of (+)- and (-)-pauciflorol F has been achieved using a recently introduced oxazolidinone controlled torquoselective Nazarov reaction. The absolute stereochemistry of pauciflorol F and its biosynthetic precursors has been unambiguously confirmed using X-ray crystallography.
Original languageEnglish
Pages (from-to)4118 - 4121
Number of pages4
JournalOrganic Letters
Volume15
Issue number16
DOIs
Publication statusPublished - 2013

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