Assessment of pre-treatment techniques for coarse printed circuit boards (PCBs) recycling

Waste electrical and electronic equipment or e-waste generation has been skyrocketing over the last decades. This poses waste management and value recovery challenges, especially in developing countries. Printed circuit boards (PCBs) are mainly employed in value recovery operations. Despite the high energy costs of generating crushed and milled particles of the order of several microns, those are employed in conventional hydrometallurgical techniques. Coarse PCB pieces (of order a few centimetres) based value recovery operations are not reported at the industrial scale as the complexities of the internal structure of PCBs limit efficient metal and non-metal separation. Since coarse PCB particles’ pre-treatment is of paramount importance to enhance metal and non-metal separations, thermal, mechanical, chemical and electrical pre-treatment techniques were extensively studied. It is quite evident that a single pre-treatment technique does not result in complete metal liberation and therefore several pre-treatment flowsheets were formulated for coarse PCB particles. Thermal, mechanical and chemical pre-treatments integrated flowsheets were derived and such flowsheets are seldom reported in the e-waste literature. The potential flowsheets need to be assessed considering socio-techno-economic considerations to yield the best available technologies (BAT). In the wider context, the results of this work could be useful for achieving the United Nations sustainable development goals.