Abstract
Compared with the corresponding reactions of 3-oxo-Δ4- steroids, hydrogenation and alkaline epoxidation of 4-methylcholestenone and 4-methyltestosterone give higher proportions of 5α-products. α-Epoxides were obtained from reactions of cholestenone and 4-methylcholestenone with peroxylauric acid.
| Original language | English |
|---|---|
| Pages (from-to) | 2469-2471 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society C: Organic Chemistry |
| DOIs | |
| Publication status | Published - 1 Dec 1967 |
| Externally published | Yes |
Cite this
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Aspects of stereochemistry. Part XXII. Epoxidation and hydrogenation of 4-methyl-3-oxo-Δ4-steroids. / Henbest, H. B.; Jackson, W. R.; Malunowicz, I.
In: Journal of the Chemical Society C: Organic Chemistry, 01.12.1967, p. 2469-2471.Research output: Contribution to journal › Article › Research › peer-review
TY - JOUR
T1 - Aspects of stereochemistry. Part XXII. Epoxidation and hydrogenation of 4-methyl-3-oxo-Δ4-steroids
AU - Henbest, H. B.
AU - Jackson, W. R.
AU - Malunowicz, I.
PY - 1967/12/1
Y1 - 1967/12/1
N2 - Compared with the corresponding reactions of 3-oxo-Δ4- steroids, hydrogenation and alkaline epoxidation of 4-methylcholestenone and 4-methyltestosterone give higher proportions of 5α-products. α-Epoxides were obtained from reactions of cholestenone and 4-methylcholestenone with peroxylauric acid.
AB - Compared with the corresponding reactions of 3-oxo-Δ4- steroids, hydrogenation and alkaline epoxidation of 4-methylcholestenone and 4-methyltestosterone give higher proportions of 5α-products. α-Epoxides were obtained from reactions of cholestenone and 4-methylcholestenone with peroxylauric acid.
UR - http://www.scopus.com/inward/record.url?scp=37049130456&partnerID=8YFLogxK
U2 - 10.1039/J39670002469
DO - 10.1039/J39670002469
M3 - Article
C2 - 6070205
AN - SCOPUS:37049130456
SP - 2469
EP - 2471
JO - Journal of the Chemical Society C: Organic Chemistry
JF - Journal of the Chemical Society C: Organic Chemistry
SN - 0022-4952
ER -