TY - JOUR
T1 - Aquabis(4-morpholinyldithiocarbamato)-iron(III) trifluoromethanesulfonate
AU - Wu, Bei
AU - Taylor, Max R.
AU - Martin, Lisandra L.
PY - 2003/11/1
Y1 - 2003/11/1
N2 - In the title compound, [Fe(C5H8NOS2) 2(H2O)]CF3SO3, the Fe atom has five-coordinate square-pyramidal stereochemistry, with the Fe atom 0.472 (1) Å above the plane of four S atoms and a water molecule O atom at the apex. The cation has m (Cs) symmetry, with the crystallographic mirror plane passing through the Fe, O and N atoms. One O atom of the anion forms a strong hydrogen bond with the coordinated water molecule [O⋯O = 2.642 (5) Å]. This is the first report of a cationic [Fe(dithiocarbamate) 2L]n+ species.
AB - In the title compound, [Fe(C5H8NOS2) 2(H2O)]CF3SO3, the Fe atom has five-coordinate square-pyramidal stereochemistry, with the Fe atom 0.472 (1) Å above the plane of four S atoms and a water molecule O atom at the apex. The cation has m (Cs) symmetry, with the crystallographic mirror plane passing through the Fe, O and N atoms. One O atom of the anion forms a strong hydrogen bond with the coordinated water molecule [O⋯O = 2.642 (5) Å]. This is the first report of a cationic [Fe(dithiocarbamate) 2L]n+ species.
UR - http://www.scopus.com/inward/record.url?scp=18544389049&partnerID=8YFLogxK
U2 - 10.1107/S1600536803024462
DO - 10.1107/S1600536803024462
M3 - Article
AN - SCOPUS:18544389049
VL - 59
JO - Acta Crystallographica Section E: Crystallographic Communications
JF - Acta Crystallographica Section E: Crystallographic Communications
SN - 2056-9890
IS - 11
ER -