Aquabis(4-morpholinyldithiocarbamato)-iron(III) trifluoromethanesulfonate

Bei Wu; Max R. Taylor; Lisandra L. Martin

doi:10.1107/S1600536803024462

Aquabis(4-morpholinyldithiocarbamato)-iron(III) trifluoromethanesulfonate

Bei Wu, Max R. Taylor, Lisandra L. Martin

Research output: Contribution to journal › Article › Research › peer-review

1 Citation (Scopus)

Abstract

In the title compound, [Fe(C₅H₈NOS₂) ₂(H₂O)]CF₃SO₃, the Fe atom has five-coordinate square-pyramidal stereochemistry, with the Fe atom 0.472 (1) Å above the plane of four S atoms and a water molecule O atom at the apex. The cation has m (C_s) symmetry, with the crystallographic mirror plane passing through the Fe, O and N atoms. One O atom of the anion forms a strong hydrogen bond with the coordinated water molecule [O⋯O = 2.642 (5) Å]. This is the first report of a cationic [Fe(dithiocarbamate) ₂L]ⁿ⁺ species.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	59
Issue number	11
DOIs	https://doi.org/10.1107/S1600536803024462
Publication status	Published - 1 Nov 2003
Externally published	Yes

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@article{8650fd2e7df34a2cbaec3c672937eb3b,

title = "Aquabis(4-morpholinyldithiocarbamato)-iron(III) trifluoromethanesulfonate",

abstract = "In the title compound, [Fe(C5H8NOS2) 2(H2O)]CF3SO3, the Fe atom has five-coordinate square-pyramidal stereochemistry, with the Fe atom 0.472 (1) {\AA} above the plane of four S atoms and a water molecule O atom at the apex. The cation has m (Cs) symmetry, with the crystallographic mirror plane passing through the Fe, O and N atoms. One O atom of the anion forms a strong hydrogen bond with the coordinated water molecule [O⋯O = 2.642 (5) {\AA}]. This is the first report of a cationic [Fe(dithiocarbamate) 2L]n+ species.",

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AU - Wu, Bei

AU - Taylor, Max R.

AU - Martin, Lisandra L.

PY - 2003/11/1

Y1 - 2003/11/1

N2 - In the title compound, [Fe(C5H8NOS2) 2(H2O)]CF3SO3, the Fe atom has five-coordinate square-pyramidal stereochemistry, with the Fe atom 0.472 (1) Å above the plane of four S atoms and a water molecule O atom at the apex. The cation has m (Cs) symmetry, with the crystallographic mirror plane passing through the Fe, O and N atoms. One O atom of the anion forms a strong hydrogen bond with the coordinated water molecule [O⋯O = 2.642 (5) Å]. This is the first report of a cationic [Fe(dithiocarbamate) 2L]n+ species.

AB - In the title compound, [Fe(C5H8NOS2) 2(H2O)]CF3SO3, the Fe atom has five-coordinate square-pyramidal stereochemistry, with the Fe atom 0.472 (1) Å above the plane of four S atoms and a water molecule O atom at the apex. The cation has m (Cs) symmetry, with the crystallographic mirror plane passing through the Fe, O and N atoms. One O atom of the anion forms a strong hydrogen bond with the coordinated water molecule [O⋯O = 2.642 (5) Å]. This is the first report of a cationic [Fe(dithiocarbamate) 2L]n+ species.

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