Application of (C4H12N2)2[BiCl6]Cl·H2O/SiO2 in the synthesis of hydratropic aldehyde and its analogs

Shipeng Nie, Wei Shen, Yuhua Gao, Yan Tang, Xiang Zhang, Xiaoyu Gu, Hongfei Lu

Research output: Contribution to journalArticleResearchpeer-review

1 Citation (Scopus)

Abstract

A highly efficient and facile procedure for the rearrangement various epoxides to carbonyl aldehydes by the catalytic system (C4H12N2)2[BiCl6]Cl·H2O/SiO2 at room temperature is developed. The methodology is applicable to a wide range of substrates. The catalyst is air-stable and environmentally friendly and can be recycled multiple times without noticeably losing its catalytic activity.

Original languageEnglish
Pages (from-to)2393-2398
Number of pages6
JournalChinese Journal of Organic Chemistry
Volume35
Issue number11
DOIs
Publication statusPublished - 1 Nov 2015
Externally publishedYes

Keywords

  • Epoxides
  • Hydratropic aldehyde
  • Lewis acid catalyst
  • Rearrangement

Cite this

Nie, Shipeng ; Shen, Wei ; Gao, Yuhua ; Tang, Yan ; Zhang, Xiang ; Gu, Xiaoyu ; Lu, Hongfei. / Application of (C4H12N2)2[BiCl6]Cl·H2O/SiO2 in the synthesis of hydratropic aldehyde and its analogs. In: Chinese Journal of Organic Chemistry. 2015 ; Vol. 35, No. 11. pp. 2393-2398.
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abstract = "A highly efficient and facile procedure for the rearrangement various epoxides to carbonyl aldehydes by the catalytic system (C4H12N2)2[BiCl6]Cl·H2O/SiO2 at room temperature is developed. The methodology is applicable to a wide range of substrates. The catalyst is air-stable and environmentally friendly and can be recycled multiple times without noticeably losing its catalytic activity.",
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Application of (C4H12N2)2[BiCl6]Cl·H2O/SiO2 in the synthesis of hydratropic aldehyde and its analogs. / Nie, Shipeng; Shen, Wei; Gao, Yuhua; Tang, Yan; Zhang, Xiang; Gu, Xiaoyu; Lu, Hongfei.

In: Chinese Journal of Organic Chemistry, Vol. 35, No. 11, 01.11.2015, p. 2393-2398.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Application of (C4H12N2)2[BiCl6]Cl·H2O/SiO2 in the synthesis of hydratropic aldehyde and its analogs

AU - Nie, Shipeng

AU - Shen, Wei

AU - Gao, Yuhua

AU - Tang, Yan

AU - Zhang, Xiang

AU - Gu, Xiaoyu

AU - Lu, Hongfei

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KW - Hydratropic aldehyde

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KW - Rearrangement

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