Anion recognition by highly sterically encumbered 1,2-diborylferrocenes

Ian R. Morgan; Alexander E.J. Broomsgrove; Philip Fitzpatrick; Dragoslav Vidovic; Amber L. Thompson; Ian A. Fallis; Simon Aldridge

doi:10.1021/om1005337

Anion recognition by highly sterically encumbered 1,2-diborylferrocenes

Ian R. Morgan
, Alexander E.J. Broomsgrove
, Philip Fitzpatrick
, Dragoslav Vidovic
, Amber L. Thompson
, Ian A. Fallis
, Simon Aldridge

Research output: Contribution to journal › Article › Research › peer-review

16 Citations (Scopus)

Abstract

The syntheses and structural characterization of sterically encumbered 1,2-diborylferrocenes are reported, together with an investigation of their anion recognition capabilities with respect to fluoride and cyanide. Surprisingly, 1,2-fc(BMes₂)₂ is found to be highly selective for CN^-, with the uptake of F^- being shown to be not only thermodynamically less favorable but also kinetically much slower.

Original language	English
Pages (from-to)	4762-4765
Number of pages	4
Journal	Organometallics
Volume	29
Issue number	21
DOIs	https://doi.org/10.1021/om1005337
Publication status	Published - 8 Nov 2010
Externally published	Yes

Access to Document

10.1021/om1005337

Cite this

@article{9b7b5f7d80b341b3a758c8bbcf93dff5,

title = "Anion recognition by highly sterically encumbered 1,2-diborylferrocenes",

abstract = "The syntheses and structural characterization of sterically encumbered 1,2-diborylferrocenes are reported, together with an investigation of their anion recognition capabilities with respect to fluoride and cyanide. Surprisingly, 1,2-fc(BMes2)2 is found to be highly selective for CN-, with the uptake of F- being shown to be not only thermodynamically less favorable but also kinetically much slower.",

author = "Morgan, \{Ian R.\} and Broomsgrove, \{Alexander E.J.\} and Philip Fitzpatrick and Dragoslav Vidovic and Thompson, \{Amber L.\} and Fallis, \{Ian A.\} and Simon Aldridge",

year = "2010",

month = nov,

day = "8",

doi = "10.1021/om1005337",

language = "English",

volume = "29",

pages = "4762--4765",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "21",

}

TY - JOUR

T1 - Anion recognition by highly sterically encumbered 1,2-diborylferrocenes

AU - Morgan, Ian R.

AU - Broomsgrove, Alexander E.J.

AU - Fitzpatrick, Philip

AU - Vidovic, Dragoslav

AU - Thompson, Amber L.

AU - Fallis, Ian A.

AU - Aldridge, Simon

PY - 2010/11/8

Y1 - 2010/11/8

N2 - The syntheses and structural characterization of sterically encumbered 1,2-diborylferrocenes are reported, together with an investigation of their anion recognition capabilities with respect to fluoride and cyanide. Surprisingly, 1,2-fc(BMes2)2 is found to be highly selective for CN-, with the uptake of F- being shown to be not only thermodynamically less favorable but also kinetically much slower.

AB - The syntheses and structural characterization of sterically encumbered 1,2-diborylferrocenes are reported, together with an investigation of their anion recognition capabilities with respect to fluoride and cyanide. Surprisingly, 1,2-fc(BMes2)2 is found to be highly selective for CN-, with the uptake of F- being shown to be not only thermodynamically less favorable but also kinetically much slower.

UR - https://www.scopus.com/pages/publications/78149336675

U2 - 10.1021/om1005337

DO - 10.1021/om1005337

M3 - Article

AN - SCOPUS:78149336675

SN - 0276-7333

VL - 29

SP - 4762

EP - 4765

JO - Organometallics

JF - Organometallics

IS - 21

ER -

Anion recognition by highly sterically encumbered 1,2-diborylferrocenes

Abstract

Access to Document

Other files and links

Cite this