Anion etching for accessing rapid and deep self-reconstruction of precatalysts for water oxidation

Yang Wang; Yinlong Zhu; Shenlong Zhao; Sixuan She; Feifei Zhang; Yu Chen; Timothy Williams; Thomas Gengenbach; Lianhai Zu; Haiyan Mao; Wei Zhou; Zongping Shao; Huanting Wang; Jing Tang; Dongyuan Zhao; Cordelia Selomulya

doi:10.1016/j.matt.2020.09.016

Anion etching for accessing rapid and deep self-reconstruction of precatalysts for water oxidation

Yang Wang, Yinlong Zhu, Shenlong Zhao, Sixuan She, Feifei Zhang, Yu Chen, Timothy Williams, Thomas Gengenbach, Lianhai Zu, Haiyan Mao, Wei Zhou, Zongping Shao, Huanting Wang, Jing Tang, Dongyuan Zhao, Cordelia Selomulya

Research output: Contribution to journal › Article › Research › peer-review

74 Citations (Scopus)

Abstract

Rapid and deep self-reconstruction (SELF-RECON) was achieved through rational design of the precatalyst. The obtained core-shell nanowired precatalyst (NiMoFeO@NC) consists of NiMoO₄ nanoparticles (core) and NiFe/NiFeO_x nanoparticles in N-doped carbons (shell). The SELF-RECON process was facilitated by rapid MoO₄²⁻ dissolution in the core of NiMoFeO@NC and fast formation of NiOOH with Fe incorporation simultaneously, which was monitored and demonstrated by in situ Raman experiments. The obtained SELF-RECONCAT outperforms NiMoFeO@NC, with ultralow overpotentials and extraordinary long-term stability.

Original language	English
Pages (from-to)	2124-2137
Number of pages	14
Journal	Matter
Volume	3
Issue number	6
DOIs	https://doi.org/10.1016/j.matt.2020.09.016
Publication status	Published - 2 Dec 2020

Keywords

anion etching
core-shell
in situ Raman spectroscopy
ion exchange
MAP2: Benchmark
nickel-iron oxyhydroxides
oxygen evolution reaction (OER)
Prussian blue analog (PBA)
SELF-RECONCAT

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10.1016/j.matt.2020.09.016

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Wang, Yang ; Zhu, Yinlong ; Zhao, Shenlong ; She, Sixuan ; Zhang, Feifei ; Chen, Yu ; Williams, Timothy ; Gengenbach, Thomas ; Zu, Lianhai ; Mao, Haiyan ; Zhou, Wei ; Shao, Zongping ; Wang, Huanting ; Tang, Jing ; Zhao, Dongyuan ; Selomulya, Cordelia. / Anion etching for accessing rapid and deep self-reconstruction of precatalysts for water oxidation. In: Matter. 2020 ; Vol. 3, No. 6. pp. 2124-2137.

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title = "Anion etching for accessing rapid and deep self-reconstruction of precatalysts for water oxidation",

abstract = "Rapid and deep self-reconstruction (SELF-RECON) was achieved through rational design of the precatalyst. The obtained core-shell nanowired precatalyst (NiMoFeO@NC) consists of NiMoO4 nanoparticles (core) and NiFe/NiFeOx nanoparticles in N-doped carbons (shell). The SELF-RECON process was facilitated by rapid MoO42− dissolution in the core of NiMoFeO@NC and fast formation of NiOOH with Fe incorporation simultaneously, which was monitored and demonstrated by in situ Raman experiments. The obtained SELF-RECONCAT outperforms NiMoFeO@NC, with ultralow overpotentials and extraordinary long-term stability.",

keywords = "anion etching, core-shell, in situ Raman spectroscopy, ion exchange, MAP2: Benchmark, nickel-iron oxyhydroxides, oxygen evolution reaction (OER), Prussian blue analog (PBA), SELF-RECONCAT",

author = "Yang Wang and Yinlong Zhu and Shenlong Zhao and Sixuan She and Feifei Zhang and Yu Chen and Timothy Williams and Thomas Gengenbach and Lianhai Zu and Haiyan Mao and Wei Zhou and Zongping Shao and Huanting Wang and Jing Tang and Dongyuan Zhao and Cordelia Selomulya",

year = "2020",

month = dec,

day = "2",

doi = "10.1016/j.matt.2020.09.016",

language = "English",

volume = "3",

pages = "2124--2137",

journal = "Matter",

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Anion etching for accessing rapid and deep self-reconstruction of precatalysts for water oxidation. / Wang, Yang; Zhu, Yinlong; Zhao, Shenlong; She, Sixuan; Zhang, Feifei; Chen, Yu; Williams, Timothy; Gengenbach, Thomas; Zu, Lianhai; Mao, Haiyan; Zhou, Wei; Shao, Zongping; Wang, Huanting; Tang, Jing; Zhao, Dongyuan; Selomulya, Cordelia.

In: Matter, Vol. 3, No. 6, 02.12.2020, p. 2124-2137.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - Anion etching for accessing rapid and deep self-reconstruction of precatalysts for water oxidation

AU - Wang, Yang

AU - Zhu, Yinlong

AU - Zhao, Shenlong

AU - She, Sixuan

AU - Zhang, Feifei

AU - Chen, Yu

AU - Williams, Timothy

AU - Gengenbach, Thomas

AU - Zu, Lianhai

AU - Mao, Haiyan

AU - Zhou, Wei

AU - Shao, Zongping

AU - Wang, Huanting

AU - Tang, Jing

AU - Zhao, Dongyuan

AU - Selomulya, Cordelia

PY - 2020/12/2

Y1 - 2020/12/2

N2 - Rapid and deep self-reconstruction (SELF-RECON) was achieved through rational design of the precatalyst. The obtained core-shell nanowired precatalyst (NiMoFeO@NC) consists of NiMoO4 nanoparticles (core) and NiFe/NiFeOx nanoparticles in N-doped carbons (shell). The SELF-RECON process was facilitated by rapid MoO42− dissolution in the core of NiMoFeO@NC and fast formation of NiOOH with Fe incorporation simultaneously, which was monitored and demonstrated by in situ Raman experiments. The obtained SELF-RECONCAT outperforms NiMoFeO@NC, with ultralow overpotentials and extraordinary long-term stability.

AB - Rapid and deep self-reconstruction (SELF-RECON) was achieved through rational design of the precatalyst. The obtained core-shell nanowired precatalyst (NiMoFeO@NC) consists of NiMoO4 nanoparticles (core) and NiFe/NiFeOx nanoparticles in N-doped carbons (shell). The SELF-RECON process was facilitated by rapid MoO42− dissolution in the core of NiMoFeO@NC and fast formation of NiOOH with Fe incorporation simultaneously, which was monitored and demonstrated by in situ Raman experiments. The obtained SELF-RECONCAT outperforms NiMoFeO@NC, with ultralow overpotentials and extraordinary long-term stability.

KW - anion etching

KW - core-shell

KW - in situ Raman spectroscopy

KW - ion exchange

KW - MAP2: Benchmark

KW - nickel-iron oxyhydroxides

KW - oxygen evolution reaction (OER)

KW - Prussian blue analog (PBA)

KW - SELF-RECONCAT

UR - http://www.scopus.com/inward/record.url?scp=85095437067&partnerID=8YFLogxK

U2 - 10.1016/j.matt.2020.09.016

DO - 10.1016/j.matt.2020.09.016

M3 - Article

AN - SCOPUS:85095437067

VL - 3

SP - 2124

EP - 2137

JO - Matter

JF - Matter

SN - 2590-2393

IS - 6

ER -

Anion etching for accessing rapid and deep self-reconstruction of precatalysts for water oxidation

Abstract

Keywords

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Advanced in-situ electron microscope facility for research in alloys, nanomaterials, functional materials, magnetic materials and minerals

Centre for Electron Microscopy (MCEM)

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Anion etching for accessing rapid and deep self-reconstruction of precatalysts for water oxidation

Abstract

Keywords

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Advanced in-situ electron microscope facility for research in alloys, nanomaterials, functional materials, magnetic materials and minerals

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Centre for Electron Microscopy (MCEM)

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