An unusual 3-D asymmetric mixed valence copper-azido complex with pyrazinecarboxylate as co-ligand showing rare net topology: Hydrothermal synthesis, structure and magnetic properties

Fu-Chen Liu; Yong-Fei Zeng; Jiong-Peng Zhao; Bo-Wen Hu; Xian-He Bu; Joan Ribas; Stuart Robert Batten

doi:10.1016/j.inoche.2006.10.002

An unusual 3-D asymmetric mixed valence copper-azido complex with pyrazinecarboxylate as co-ligand showing rare net topology: Hydrothermal synthesis, structure and magnetic properties

Fu-Chen Liu, Yong-Fei Zeng, Jiong-Peng Zhao, Bo-Wen Hu, Xian-He Bu, Joan Ribas, Stuart Robert Batten

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

19 Citations (Scopus)

Abstract

A new 3-D mixed valence copper-azido coordination polymer, [CuI · CuII(N3)(pzc)2 (H2O)]n1, has been synthesized and characterized, and its magnetic properties studied. In this compound, the azide acts as rare asymmetric μ1,1,3 bridging mode. The azide ligands and the Cu(2) ions act as 3-connecting nodes, and the Cu(1) ions act as 4-connecting nodes. The overall net takes rare topology with the Schläfli symbol of (6.82)(6.82)(6.85).

Original language	English
Pages (from-to)	129-132
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	2
DOIs	https://doi.org/10.1016/j.inoche.2006.10.002
Publication status	Published - 2007

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10.1016/j.inoche.2006.10.002

Cite this

Liu, F-C., Zeng, Y-F., Zhao, J-P., Hu, B-W., Bu, X-H., Ribas, J., & Batten, S. R. (2007). An unusual 3-D asymmetric mixed valence copper-azido complex with pyrazinecarboxylate as co-ligand showing rare net topology: Hydrothermal synthesis, structure and magnetic properties. Inorganic Chemistry Communications, 10(2), 129-132. https://doi.org/10.1016/j.inoche.2006.10.002

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title = "An unusual 3-D asymmetric mixed valence copper-azido complex with pyrazinecarboxylate as co-ligand showing rare net topology: Hydrothermal synthesis, structure and magnetic properties",

abstract = "A new 3-D mixed valence copper-azido coordination polymer, [CuI · CuII(N3)(pzc)2 (H2O)]n1, has been synthesized and characterized, and its magnetic properties studied. In this compound, the azide acts as rare asymmetric μ1,1,3 bridging mode. The azide ligands and the Cu(2) ions act as 3-connecting nodes, and the Cu(1) ions act as 4-connecting nodes. The overall net takes rare topology with the Schl{\"a}fli symbol of (6.82)(6.82)(6.85).",

author = "Fu-Chen Liu and Yong-Fei Zeng and Jiong-Peng Zhao and Bo-Wen Hu and Xian-He Bu and Joan Ribas and Batten, {Stuart Robert}",

year = "2007",

doi = "10.1016/j.inoche.2006.10.002",

language = "English",

volume = "10",

pages = "129--132",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "2",

}

Liu, F-C, Zeng, Y-F, Zhao, J-P, Hu, B-W, Bu, X-H, Ribas, J & Batten, SR 2007, 'An unusual 3-D asymmetric mixed valence copper-azido complex with pyrazinecarboxylate as co-ligand showing rare net topology: Hydrothermal synthesis, structure and magnetic properties', Inorganic Chemistry Communications, vol. 10, no. 2, pp. 129-132. https://doi.org/10.1016/j.inoche.2006.10.002

An unusual 3-D asymmetric mixed valence copper-azido complex with pyrazinecarboxylate as co-ligand showing rare net topology: Hydrothermal synthesis, structure and magnetic properties. / Liu, Fu-Chen; Zeng, Yong-Fei; Zhao, Jiong-Peng et al.

In: Inorganic Chemistry Communications, Vol. 10, No. 2, 2007, p. 129-132.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - An unusual 3-D asymmetric mixed valence copper-azido complex with pyrazinecarboxylate as co-ligand showing rare net topology: Hydrothermal synthesis, structure and magnetic properties

AU - Liu, Fu-Chen

AU - Zeng, Yong-Fei

AU - Zhao, Jiong-Peng

AU - Hu, Bo-Wen

AU - Bu, Xian-He

AU - Ribas, Joan

AU - Batten, Stuart Robert

PY - 2007

Y1 - 2007

N2 - A new 3-D mixed valence copper-azido coordination polymer, [CuI · CuII(N3)(pzc)2 (H2O)]n1, has been synthesized and characterized, and its magnetic properties studied. In this compound, the azide acts as rare asymmetric μ1,1,3 bridging mode. The azide ligands and the Cu(2) ions act as 3-connecting nodes, and the Cu(1) ions act as 4-connecting nodes. The overall net takes rare topology with the Schläfli symbol of (6.82)(6.82)(6.85).

AB - A new 3-D mixed valence copper-azido coordination polymer, [CuI · CuII(N3)(pzc)2 (H2O)]n1, has been synthesized and characterized, and its magnetic properties studied. In this compound, the azide acts as rare asymmetric μ1,1,3 bridging mode. The azide ligands and the Cu(2) ions act as 3-connecting nodes, and the Cu(1) ions act as 4-connecting nodes. The overall net takes rare topology with the Schläfli symbol of (6.82)(6.82)(6.85).

U2 - 10.1016/j.inoche.2006.10.002

DO - 10.1016/j.inoche.2006.10.002

M3 - Article

VL - 10

SP - 129

EP - 132

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

SN - 1387-7003

IS - 2

ER -