An unusual 3-D asymmetric mixed valence copper-azido complex with pyrazinecarboxylate as co-ligand showing rare net topology: Hydrothermal synthesis, structure and magnetic properties

Fu-Chen Liu, Yong-Fei Zeng, Jiong-Peng Zhao, Bo-Wen Hu, Xian-He Bu, Joan Ribas, Stuart Robert Batten

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18 Citations (Scopus)

Abstract

A new 3-D mixed valence copper-azido coordination polymer, [CuI · CuII(N3)(pzc)2 (H2O)]n1, has been synthesized and characterized, and its magnetic properties studied. In this compound, the azide acts as rare asymmetric μ1,1,3 bridging mode. The azide ligands and the Cu(2) ions act as 3-connecting nodes, and the Cu(1) ions act as 4-connecting nodes. The overall net takes rare topology with the Schläfli symbol of (6.82)(6.82)(6.85).
Original languageEnglish
Pages (from-to)129-132
Number of pages4
JournalInorganic Chemistry Communications
Volume10
Issue number2
DOIs
Publication statusPublished - 2007

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