An uncommon 3D Co5-cluster-based metal-organic framework: Synthesis, structure and magnetism

Yu Wu, Bao-Hong Li, Jian Qiang Liu, Bing Xie, Hiroshi Sakiyama, Stuart R. Batten

Research output: Contribution to journalArticleOtherpeer-review

6 Citations (Scopus)

Abstract

A highly connected metal–organic framework (MOF), namely, [Co53-OH)2(iapt)4(4,4′-bipy)0.5(H2O)·CH3CN·3H2O] (1) (H2iapt = 5-aminoisophthalic acid and 4,4′-bipy = 4,4′-bipyridine), is reported. 1 shows a complicated pentanodal 4,4,4,4,13-c 3D net with (43)(43)(43)(43)(420·514·623·78·813) topology based on an uncommon Co5 cluster. The magnetic analysis reveals antiferromagnetic interactions in 1, and both the local spin–orbit coupling of octahedral Co(II) ions and the antiferromagnetic interactions are the primary factors in the magnetic behaviour.

Original languageEnglish
Pages (from-to)24-26
Number of pages3
JournalInorganic Chemistry Communication
Volume82
DOIs
Publication statusPublished - 1 Aug 2017

Keywords

  • Cluster
  • Co(II)-MOF
  • High connection
  • Magnetism

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