An uncommon 3D Co5-cluster-based metal-organic framework

Synthesis, structure and magnetism

Yu Wu, Bao-Hong Li, Jian Qiang Liu, Bing Xie, Hiroshi Sakiyama, Stuart R. Batten

Research output: Contribution to journalArticleOtherpeer-review

5 Citations (Scopus)

Abstract

A highly connected metal–organic framework (MOF), namely, [Co53-OH)2(iapt)4(4,4′-bipy)0.5(H2O)·CH3CN·3H2O] (1) (H2iapt = 5-aminoisophthalic acid and 4,4′-bipy = 4,4′-bipyridine), is reported. 1 shows a complicated pentanodal 4,4,4,4,13-c 3D net with (43)(43)(43)(43)(420·514·623·78·813) topology based on an uncommon Co5 cluster. The magnetic analysis reveals antiferromagnetic interactions in 1, and both the local spin–orbit coupling of octahedral Co(II) ions and the antiferromagnetic interactions are the primary factors in the magnetic behaviour.

Original languageEnglish
Pages (from-to)24-26
Number of pages3
JournalInorganic Chemistry Communication
Volume82
DOIs
Publication statusPublished - 1 Aug 2017

Keywords

  • Cluster
  • Co(II)-MOF
  • High connection
  • Magnetism

Cite this

Wu, Yu ; Li, Bao-Hong ; Liu, Jian Qiang ; Xie, Bing ; Sakiyama, Hiroshi ; Batten, Stuart R. / An uncommon 3D Co5-cluster-based metal-organic framework : Synthesis, structure and magnetism. In: Inorganic Chemistry Communication. 2017 ; Vol. 82. pp. 24-26.
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abstract = "A highly connected metal–organic framework (MOF), namely, [Co5(μ3-OH)2(iapt)4(4,4′-bipy)0.5(H2O)·CH3CN·3H2O] (1) (H2iapt = 5-aminoisophthalic acid and 4,4′-bipy = 4,4′-bipyridine), is reported. 1 shows a complicated pentanodal 4,4,4,4,13-c 3D net with (43)(43)(43)(43)(420·514·623·78·813) topology based on an uncommon Co5 cluster. The magnetic analysis reveals antiferromagnetic interactions in 1, and both the local spin–orbit coupling of octahedral Co(II) ions and the antiferromagnetic interactions are the primary factors in the magnetic behaviour.",
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An uncommon 3D Co5-cluster-based metal-organic framework : Synthesis, structure and magnetism. / Wu, Yu; Li, Bao-Hong; Liu, Jian Qiang; Xie, Bing; Sakiyama, Hiroshi; Batten, Stuart R.

In: Inorganic Chemistry Communication, Vol. 82, 01.08.2017, p. 24-26.

Research output: Contribution to journalArticleOtherpeer-review

TY - JOUR

T1 - An uncommon 3D Co5-cluster-based metal-organic framework

T2 - Synthesis, structure and magnetism

AU - Wu, Yu

AU - Li, Bao-Hong

AU - Liu, Jian Qiang

AU - Xie, Bing

AU - Sakiyama, Hiroshi

AU - Batten, Stuart R.

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AB - A highly connected metal–organic framework (MOF), namely, [Co5(μ3-OH)2(iapt)4(4,4′-bipy)0.5(H2O)·CH3CN·3H2O] (1) (H2iapt = 5-aminoisophthalic acid and 4,4′-bipy = 4,4′-bipyridine), is reported. 1 shows a complicated pentanodal 4,4,4,4,13-c 3D net with (43)(43)(43)(43)(420·514·623·78·813) topology based on an uncommon Co5 cluster. The magnetic analysis reveals antiferromagnetic interactions in 1, and both the local spin–orbit coupling of octahedral Co(II) ions and the antiferromagnetic interactions are the primary factors in the magnetic behaviour.

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KW - Co(II)-MOF

KW - High connection

KW - Magnetism

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