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There is growing interest in developing sodium based energy storage devices as alternatives to Li for large-scale energy storage. We report a highly stable hybrid system comprising a sodium metal anode, a highly porous N/S co-doped mesoporous carbon cathode and the non-flammable ionic liquid electrolyte N-propyl-N-methyl pyrrolidinium bis(fluorosulfonyl) imide (C 3 mpyrFSI). This hybrid device operates at 100% coulombic efficiency and shows almost complete capacity retention over 3000 cycles. Owing to the reversible cathode reactions between Na + and N/S functionalities on the carbon surface, a very high capacity of 716 mA h g -1 (at a rate of C/16) was achieved between 3.8 V and 0.005 V vs. Na + /Na. An optimised device could provide energy density as high as 263 W h kg -1 . At high rate, the devices achieved power density of 1463 W kg -1 . These metrics increase to 270 W h kg -1 and 3822 W kg -1 at 50 °C, highlighting the excellent combination of a supercapacitor-type cathode with a sodium metal anode and an ionic liquid electrolyte for large-scale energy storage.
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