An investigation of commercial carbon air cathode structure in ionic liquid based sodium oxygen batteries

The An Ha, Cristina Pozo-Gonzalo, Kate Nairn, Douglas R. MacFarlane, Maria Forsyth, Patrick C. Howlett

Research output: Contribution to journalArticleResearchpeer-review

5 Citations (Scopus)

Abstract

In order to bridge the gap between theoretical and practical energy density in sodium oxygen batteries challenges need to be overcome. In this work, four commercial air cathodes were selected, and the impacts of their morphologies, structure and chemistry on their performance with a pyrrolidinium-based ionic liquid electrolyte are evaluated. The highest discharge capacity was found for a cathode with a pore size ca. 6 nm; this was over 100 times greater than that delivered by a cathode with a pore size less than 2 nm. The air cathode with the highest specific surface area and the presence of a microporous layer (BC39) exhibited the highest specific capacity (0.53 mAh cm−2).

Original languageEnglish
Article number7123
Number of pages10
JournalScientific Reports
Volume10
Issue number1
DOIs
Publication statusPublished - 28 Apr 2020

Keywords

  • energy
  • materials for energy and catalysis

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