An interpenetrating coordination polymer containing weak hydrogen bonds and argentophilic interactions

Martin Duriska; Stuart Robert Batten; David J Price

doi:10.1071/CH05304

An interpenetrating coordination polymer containing weak hydrogen bonds and argentophilic interactions

Martin Duriska
, Stuart Robert Batten
, David J Price

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

42 Citations (Scopus)

Abstract

The structure of the coordination polymer [Ni(en)2][Ag(CN) 2]2[Ag2(CN)2] (1; en = ethylenediamine) contains 2D (6,3) sheets in which trans-Ni(en) 2{Ag(CN)2}2 moieties bridge between zigzag Ag(CN) chains. The sheets are puckered, and show 3-fold 2D → 2D parallel interpenetration. The structure also contains weak N-H⋯π(CN) and argentophilic Ag⋯Ag interactions between the 2D sheets.

Original language	English
Pages (from-to)	26-29
Number of pages	4
Journal	Australian Journal of Chemistry
Volume	59
Issue number	1
DOIs	https://doi.org/10.1071/CH05304
Publication status	Published - 2006

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10.1071/CH05304

Cite this

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abstract = "The structure of the coordination polymer [Ni(en)2][Ag(CN) 2]2[Ag2(CN)2] (1; en = ethylenediamine) contains 2D (6,3) sheets in which trans-Ni(en) 2\{Ag(CN)2\}2 moieties bridge between zigzag Ag(CN) chains. The sheets are puckered, and show 3-fold 2D → 2D parallel interpenetration. The structure also contains weak N-H⋯π(CN) and argentophilic Ag⋯Ag interactions between the 2D sheets.",

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AB - The structure of the coordination polymer [Ni(en)2][Ag(CN) 2]2[Ag2(CN)2] (1; en = ethylenediamine) contains 2D (6,3) sheets in which trans-Ni(en) 2{Ag(CN)2}2 moieties bridge between zigzag Ag(CN) chains. The sheets are puckered, and show 3-fold 2D → 2D parallel interpenetration. The structure also contains weak N-H⋯π(CN) and argentophilic Ag⋯Ag interactions between the 2D sheets.

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