An inclined interpenetrating heteropolynuclear polymer with unusual propagation of metal carboxylate secondary building units by both carboxylate and pyridyl bridging ligands

Peng Chen, Yun-Xia Che, Stuart Robert Batten, Ji-Min Zheng

Research output: Contribution to journalArticleResearchpeer-review

15 Citations (Scopus)

Abstract

The objective of this paper is to describe an unusual coordination polymer, M-4(mu(4)-O)(bipy)(m-BDC)(3) (sM(4) = Zn-2.36 Co-1.64, bipy = 4,4 -bipyridine, m-H2BDC = 1,3-benzenedicarboxylic acid) (1), which has been hydrothermally synthesised and characterized by single-crystal X-ray diffraction, XRPD, IR, TGA, ICP, atomic absorption, and element analysis. 1 crystallizes in the P4(2)/mnm space group and contains a M4O(O2C)(6) secondary building unit (SBU) with an inclined interpenetrated (4,4) topology, and is a rare combination of the two most successful approaches to coordination polymer design: generation of metal carboxylate SBUs and the use of pyridyl donor bridges. Moreover, complex 1 exhibits intense fluorescence at about 424 nm (lambda(ex) = 312 nm) in the solid state. (c) 2006 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)415 - 418
Number of pages4
JournalInorganic Chemistry Communication
Volume10
Issue number4
Publication statusPublished - 2007

Cite this

@article{3482f9882c7f47f49c035fd2a31bb4c0,
title = "An inclined interpenetrating heteropolynuclear polymer with unusual propagation of metal carboxylate secondary building units by both carboxylate and pyridyl bridging ligands",
abstract = "The objective of this paper is to describe an unusual coordination polymer, M-4(mu(4)-O)(bipy)(m-BDC)(3) (sM(4) = Zn-2.36 Co-1.64, bipy = 4,4 -bipyridine, m-H2BDC = 1,3-benzenedicarboxylic acid) (1), which has been hydrothermally synthesised and characterized by single-crystal X-ray diffraction, XRPD, IR, TGA, ICP, atomic absorption, and element analysis. 1 crystallizes in the P4(2)/mnm space group and contains a M4O(O2C)(6) secondary building unit (SBU) with an inclined interpenetrated (4,4) topology, and is a rare combination of the two most successful approaches to coordination polymer design: generation of metal carboxylate SBUs and the use of pyridyl donor bridges. Moreover, complex 1 exhibits intense fluorescence at about 424 nm (lambda(ex) = 312 nm) in the solid state. (c) 2006 Elsevier B.V. All rights reserved.",
author = "Peng Chen and Yun-Xia Che and Batten, {Stuart Robert} and Ji-Min Zheng",
year = "2007",
language = "English",
volume = "10",
pages = "415 -- 418",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier",
number = "4",

}

An inclined interpenetrating heteropolynuclear polymer with unusual propagation of metal carboxylate secondary building units by both carboxylate and pyridyl bridging ligands. / Chen, Peng; Che, Yun-Xia; Batten, Stuart Robert; Zheng, Ji-Min.

In: Inorganic Chemistry Communication, Vol. 10, No. 4, 2007, p. 415 - 418.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - An inclined interpenetrating heteropolynuclear polymer with unusual propagation of metal carboxylate secondary building units by both carboxylate and pyridyl bridging ligands

AU - Chen, Peng

AU - Che, Yun-Xia

AU - Batten, Stuart Robert

AU - Zheng, Ji-Min

PY - 2007

Y1 - 2007

N2 - The objective of this paper is to describe an unusual coordination polymer, M-4(mu(4)-O)(bipy)(m-BDC)(3) (sM(4) = Zn-2.36 Co-1.64, bipy = 4,4 -bipyridine, m-H2BDC = 1,3-benzenedicarboxylic acid) (1), which has been hydrothermally synthesised and characterized by single-crystal X-ray diffraction, XRPD, IR, TGA, ICP, atomic absorption, and element analysis. 1 crystallizes in the P4(2)/mnm space group and contains a M4O(O2C)(6) secondary building unit (SBU) with an inclined interpenetrated (4,4) topology, and is a rare combination of the two most successful approaches to coordination polymer design: generation of metal carboxylate SBUs and the use of pyridyl donor bridges. Moreover, complex 1 exhibits intense fluorescence at about 424 nm (lambda(ex) = 312 nm) in the solid state. (c) 2006 Elsevier B.V. All rights reserved.

AB - The objective of this paper is to describe an unusual coordination polymer, M-4(mu(4)-O)(bipy)(m-BDC)(3) (sM(4) = Zn-2.36 Co-1.64, bipy = 4,4 -bipyridine, m-H2BDC = 1,3-benzenedicarboxylic acid) (1), which has been hydrothermally synthesised and characterized by single-crystal X-ray diffraction, XRPD, IR, TGA, ICP, atomic absorption, and element analysis. 1 crystallizes in the P4(2)/mnm space group and contains a M4O(O2C)(6) secondary building unit (SBU) with an inclined interpenetrated (4,4) topology, and is a rare combination of the two most successful approaches to coordination polymer design: generation of metal carboxylate SBUs and the use of pyridyl donor bridges. Moreover, complex 1 exhibits intense fluorescence at about 424 nm (lambda(ex) = 312 nm) in the solid state. (c) 2006 Elsevier B.V. All rights reserved.

UR - http://<Go to ISI>://000245310300009

M3 - Article

VL - 10

SP - 415

EP - 418

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

IS - 4

ER -