An EPR microwave saturation study of Co2+ in a zirconium fluoride-based glass

J. O. Warne, G. Hanson, J. R. Pilbrow, D. R. MacFarlane

Research output: Contribution to journalArticleResearchpeer-review

7 Citations (Scopus)

Abstract

Optical and electron paramagnetic resonance (EPR) spectroscopies have been used to investigate the coordination number and site symmetry of Co2+ in a heavy metal fluoride glass. From EPR microwave saturation measurements, the zero field splitting of the Co2+ ion doped into a ZBL glass was determined. It was deduced from this that the Co2+ resides in a site of cubic symmetry.

Original languageEnglish
Pages (from-to)319-323
Number of pages5
JournalJournal of Non-Crystalline Solids
Volume140
Issue numberC
DOIs
Publication statusPublished - 1 Jan 1992

Cite this

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An EPR microwave saturation study of Co2+ in a zirconium fluoride-based glass. / Warne, J. O.; Hanson, G.; Pilbrow, J. R.; MacFarlane, D. R.

In: Journal of Non-Crystalline Solids, Vol. 140, No. C, 01.01.1992, p. 319-323.

Research output: Contribution to journalArticleResearchpeer-review

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T1 - An EPR microwave saturation study of Co2+ in a zirconium fluoride-based glass

AU - Warne, J. O.

AU - Hanson, G.

AU - Pilbrow, J. R.

AU - MacFarlane, D. R.

PY - 1992/1/1

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N2 - Optical and electron paramagnetic resonance (EPR) spectroscopies have been used to investigate the coordination number and site symmetry of Co2+ in a heavy metal fluoride glass. From EPR microwave saturation measurements, the zero field splitting of the Co2+ ion doped into a ZBL glass was determined. It was deduced from this that the Co2+ resides in a site of cubic symmetry.

AB - Optical and electron paramagnetic resonance (EPR) spectroscopies have been used to investigate the coordination number and site symmetry of Co2+ in a heavy metal fluoride glass. From EPR microwave saturation measurements, the zero field splitting of the Co2+ ion doped into a ZBL glass was determined. It was deduced from this that the Co2+ resides in a site of cubic symmetry.

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DO - 10.1016/S0022-3093(05)80789-6

M3 - Article

VL - 140

SP - 319

EP - 323

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

SN - 0022-3093

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ER -