An EPR microwave saturation study of Co2+ in a zirconium fluoride-based glass

J. O. Warne, G. Hanson, J. R. Pilbrow, D. R. MacFarlane

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Abstract

Optical and electron paramagnetic resonance (EPR) spectroscopies have been used to investigate the coordination number and site symmetry of Co2+ in a heavy metal fluoride glass. From EPR microwave saturation measurements, the zero field splitting of the Co2+ ion doped into a ZBL glass was determined. It was deduced from this that the Co2+ resides in a site of cubic symmetry.

Original languageEnglish
Pages (from-to)319-323
Number of pages5
JournalJournal of Non-Crystalline Solids
Volume140
Issue numberC
DOIs
Publication statusPublished - 1 Jan 1992

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