An application of rapid polarographic techniques and the derivation of an equation for the polarographic study of the fluoride complexes of bismuth(III) in acid media

A. M. Bond

An application of rapid polarographic techniques and the derivation of an equation for the polarographic study of the fluoride complexes of bismuth(III) in acid media

Research output: Contribution to journal › Article › Research › peer-review

Abstract

Polarographic measurements on acidic solutions of Bi(III) and fluoride have indicated the existence of the species: BiF²⁺, BiF⁺₂ and BiF₃, with stability constants (at ionic strength of 2.0 and at 30°C) of 26, 2 and 500, respectively, for the reaction: Bi³⁺+nHF⇌BiF^(3-n)+_n + nH⁺. Results have been interpreted on the basis of change in half-wave potential with change in fluoride concentration and under conditions in which reversible reduction of Bi(III) was found to occur.

Original language	English
Pages (from-to)	269-276
Number of pages	8
Journal	Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
Volume	23
Issue number	2
Publication status	Published - Nov 1969
Externally published	Yes

Cite this

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title = "An application of rapid polarographic techniques and the derivation of an equation for the polarographic study of the fluoride complexes of bismuth(III) in acid media",

abstract = "Polarographic measurements on acidic solutions of Bi(III) and fluoride have indicated the existence of the species: BiF2+, BiF+2 and BiF3, with stability constants (at ionic strength of 2.0 and at 30°C) of 26, 2 and 500, respectively, for the reaction: Bi3++nHF⇌BiF(3-n)+n + nH+. Results have been interpreted on the basis of change in half-wave potential with change in fluoride concentration and under conditions in which reversible reduction of Bi(III) was found to occur.",

author = "Bond, {A. M.}",

year = "1969",

month = nov,

language = "English",

volume = "23",

pages = "269--276",

journal = "Journal of Electroanalytical Chemistry",

issn = "1572-6657",

publisher = "Elsevier",

number = "2",

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An application of rapid polarographic techniques and the derivation of an equation for the polarographic study of the fluoride complexes of bismuth(III) in acid media. / Bond, A. M.
In: Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 23, No. 2, 11.1969, p. 269-276.

Research output: Contribution to journal › Article › Research › peer-review

TY - JOUR

T1 - An application of rapid polarographic techniques and the derivation of an equation for the polarographic study of the fluoride complexes of bismuth(III) in acid media

AU - Bond, A. M.

PY - 1969/11

Y1 - 1969/11

N2 - Polarographic measurements on acidic solutions of Bi(III) and fluoride have indicated the existence of the species: BiF2+, BiF+2 and BiF3, with stability constants (at ionic strength of 2.0 and at 30°C) of 26, 2 and 500, respectively, for the reaction: Bi3++nHF⇌BiF(3-n)+n + nH+. Results have been interpreted on the basis of change in half-wave potential with change in fluoride concentration and under conditions in which reversible reduction of Bi(III) was found to occur.

AB - Polarographic measurements on acidic solutions of Bi(III) and fluoride have indicated the existence of the species: BiF2+, BiF+2 and BiF3, with stability constants (at ionic strength of 2.0 and at 30°C) of 26, 2 and 500, respectively, for the reaction: Bi3++nHF⇌BiF(3-n)+n + nH+. Results have been interpreted on the basis of change in half-wave potential with change in fluoride concentration and under conditions in which reversible reduction of Bi(III) was found to occur.

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SN - 1572-6657

VL - 23

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EP - 276

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

IS - 2

ER -

An application of rapid polarographic techniques and the derivation of an equation for the polarographic study of the fluoride complexes of bismuth(III) in acid media

Abstract

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