Ammonium heptanitrosyltrithiotetraferrate monohydrate

Lisandra L. Martin; Gary D. Fallon; Bei Wu

doi:10.1107/S1600536804002338

Ammonium heptanitrosyltrithiotetraferrate monohydrate

Lisandra L. Martin, Gary D. Fallon, Bei Wu

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

4 Citations (Scopus)

Abstract

The title compound, (NH₄)[Fe₄S₃(NO) ₇]·H₂O, contains an Fe₄S₃ partial cubane core in which the apical iron is coordinated by one nitrosyl group and three S atoms above the plane of three Fe atoms. These three Fe atoms are in turn each coordinated by two S atoms and two nitrosyl groups. The axial O atoms hydrogen bond with the ammonium cation, creating a 'tight' ion-pair, consistent with the solubility of the salt in diethyl ether.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	3
DOIs	https://doi.org/10.1107/S1600536804002338
Publication status	Published - 1 Mar 2004

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title = "Ammonium heptanitrosyltrithiotetraferrate monohydrate",

abstract = "The title compound, (NH4)[Fe4S3(NO) 7]·H2O, contains an Fe4S3 partial cubane core in which the apical iron is coordinated by one nitrosyl group and three S atoms above the plane of three Fe atoms. These three Fe atoms are in turn each coordinated by two S atoms and two nitrosyl groups. The axial O atoms hydrogen bond with the ammonium cation, creating a 'tight' ion-pair, consistent with the solubility of the salt in diethyl ether.",

author = "Martin, \{Lisandra L.\} and Fallon, \{Gary D.\} and Bei Wu",

year = "2004",

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T1 - Ammonium heptanitrosyltrithiotetraferrate monohydrate

AU - Martin, Lisandra L.

AU - Fallon, Gary D.

AU - Wu, Bei

PY - 2004/3/1

Y1 - 2004/3/1

N2 - The title compound, (NH4)[Fe4S3(NO) 7]·H2O, contains an Fe4S3 partial cubane core in which the apical iron is coordinated by one nitrosyl group and three S atoms above the plane of three Fe atoms. These three Fe atoms are in turn each coordinated by two S atoms and two nitrosyl groups. The axial O atoms hydrogen bond with the ammonium cation, creating a 'tight' ion-pair, consistent with the solubility of the salt in diethyl ether.

AB - The title compound, (NH4)[Fe4S3(NO) 7]·H2O, contains an Fe4S3 partial cubane core in which the apical iron is coordinated by one nitrosyl group and three S atoms above the plane of three Fe atoms. These three Fe atoms are in turn each coordinated by two S atoms and two nitrosyl groups. The axial O atoms hydrogen bond with the ammonium cation, creating a 'tight' ion-pair, consistent with the solubility of the salt in diethyl ether.

UR - https://www.scopus.com/pages/publications/18444392076

U2 - 10.1107/S1600536804002338

DO - 10.1107/S1600536804002338

M3 - Article

AN - SCOPUS:18444392076

SN - 1600-5368

VL - 60

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

Ammonium heptanitrosyltrithiotetraferrate monohydrate

Abstract

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