Ammonium heptanitrosyltrithiotetraferrate monohydrate

Lisandra L. Martin; Gary D. Fallon; Bei Wu

doi:10.1107/S1600536804002338

Ammonium heptanitrosyltrithiotetraferrate monohydrate

Lisandra L. Martin, Gary D. Fallon, Bei Wu

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

4 Citations (Scopus)

Abstract

The title compound, (NH₄)[Fe₄S₃(NO) ₇]·H₂O, contains an Fe₄S₃ partial cubane core in which the apical iron is coordinated by one nitrosyl group and three S atoms above the plane of three Fe atoms. These three Fe atoms are in turn each coordinated by two S atoms and two nitrosyl groups. The axial O atoms hydrogen bond with the ammonium cation, creating a 'tight' ion-pair, consistent with the solubility of the salt in diethyl ether.

Original language	English
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	60
Issue number	3
DOIs	https://doi.org/10.1107/S1600536804002338
Publication status	Published - 1 Mar 2004

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title = "Ammonium heptanitrosyltrithiotetraferrate monohydrate",

abstract = "The title compound, (NH4)[Fe4S3(NO) 7]·H2O, contains an Fe4S3 partial cubane core in which the apical iron is coordinated by one nitrosyl group and three S atoms above the plane of three Fe atoms. These three Fe atoms are in turn each coordinated by two S atoms and two nitrosyl groups. The axial O atoms hydrogen bond with the ammonium cation, creating a 'tight' ion-pair, consistent with the solubility of the salt in diethyl ether.",

author = "Martin, {Lisandra L.} and Fallon, {Gary D.} and Bei Wu",

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AU - Martin, Lisandra L.

AU - Fallon, Gary D.

AU - Wu, Bei

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N2 - The title compound, (NH4)[Fe4S3(NO) 7]·H2O, contains an Fe4S3 partial cubane core in which the apical iron is coordinated by one nitrosyl group and three S atoms above the plane of three Fe atoms. These three Fe atoms are in turn each coordinated by two S atoms and two nitrosyl groups. The axial O atoms hydrogen bond with the ammonium cation, creating a 'tight' ion-pair, consistent with the solubility of the salt in diethyl ether.

AB - The title compound, (NH4)[Fe4S3(NO) 7]·H2O, contains an Fe4S3 partial cubane core in which the apical iron is coordinated by one nitrosyl group and three S atoms above the plane of three Fe atoms. These three Fe atoms are in turn each coordinated by two S atoms and two nitrosyl groups. The axial O atoms hydrogen bond with the ammonium cation, creating a 'tight' ion-pair, consistent with the solubility of the salt in diethyl ether.

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DO - 10.1107/S1600536804002338

M3 - Article

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JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

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Ammonium heptanitrosyltrithiotetraferrate monohydrate

Abstract

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