Amine elimination synthesis of a titanium(IV) N-heterocyclic carbene complex with short intramolecular Cl⋯Ccarbene contacts

Piyush Shukla, Jennifer A. Johnson, Dragosla Vidovic, Alan H. Cowley, Colin D. Abernethy

Research output: Contribution to journalArticleResearchpeer-review

67 Citations (Scopus)


The reaction of 1,3-dimesitylimidazolium chloride with Ti(NMe2)4 results in the 1,3-dimesitylimadazol-2-ylidene complex of Ti(NMe2)2Cl2(3); the X-ray crystal structure of 3 evidences short intramolecular Cl⋯Ccarbene contacts.

Original languageEnglish
Pages (from-to)360-361
Number of pages2
JournalChemical Communications
Issue number4
Publication statusPublished - 1 Jan 2004
Externally publishedYes

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