Aluminum Complexes in Organic Synthesis

Dragoslav Vidović

doi:10.1016/B978-0-12-820206-7.00052-4

Aluminum Complexes in Organic Synthesis

Dragoslav Vidović

School of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Encyclopaedia / Dictionary Entry › Other › peer-review

Abstract

Developments in homogenous catalysis using aluminum complexes that have been disclosed to the research community in the last 15years, i.e. from 2006 till early 2021, are communicated. Reductions (e.g. hydroboration), oxidations (Oppenauer oxidation), additions (Mukaiyama aldol) and cyclizations (Diels Alder) are among a number of organic transformations that have been catalyzed by aluminum complexes in recent years. The chapter also includes an important discussion about the importance of identifying the catalytically active species especially as it pertains to the use of aluminum complexes in Lewis acid catalysis.

Original language	English
Title of host publication	Comprehensive Organometallic Chemistry IV
Subtitle of host publication	Volume 1-15
Editors	David J. Liptrot
Publisher	Elsevier
Chapter	11.08
Pages	335-381
Number of pages	47
Volume	11
Edition	4th
ISBN (Electronic)	9780128202067
ISBN (Print)	9780323913508
DOIs	https://doi.org/10.1016/B978-0-12-820206-7.00052-4
Publication status	Published - 2022

Keywords

Addition
Aluminum
Catalysis
Cyclization
Hidden boron catalysis
Hidden Brønsted acid catalysis
Homogenous
Oxidation
Reduction

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10.1016/B978-0-12-820206-7.00052-4

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title = "Aluminum Complexes in Organic Synthesis",

abstract = "Developments in homogenous catalysis using aluminum complexes that have been disclosed to the research community in the last 15years, i.e. from 2006 till early 2021, are communicated. Reductions (e.g. hydroboration), oxidations (Oppenauer oxidation), additions (Mukaiyama aldol) and cyclizations (Diels Alder) are among a number of organic transformations that have been catalyzed by aluminum complexes in recent years. The chapter also includes an important discussion about the importance of identifying the catalytically active species especially as it pertains to the use of aluminum complexes in Lewis acid catalysis.",

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T1 - Aluminum Complexes in Organic Synthesis

AU - Vidović, Dragoslav

PY - 2022

Y1 - 2022

N2 - Developments in homogenous catalysis using aluminum complexes that have been disclosed to the research community in the last 15years, i.e. from 2006 till early 2021, are communicated. Reductions (e.g. hydroboration), oxidations (Oppenauer oxidation), additions (Mukaiyama aldol) and cyclizations (Diels Alder) are among a number of organic transformations that have been catalyzed by aluminum complexes in recent years. The chapter also includes an important discussion about the importance of identifying the catalytically active species especially as it pertains to the use of aluminum complexes in Lewis acid catalysis.

AB - Developments in homogenous catalysis using aluminum complexes that have been disclosed to the research community in the last 15years, i.e. from 2006 till early 2021, are communicated. Reductions (e.g. hydroboration), oxidations (Oppenauer oxidation), additions (Mukaiyama aldol) and cyclizations (Diels Alder) are among a number of organic transformations that have been catalyzed by aluminum complexes in recent years. The chapter also includes an important discussion about the importance of identifying the catalytically active species especially as it pertains to the use of aluminum complexes in Lewis acid catalysis.

KW - Addition

KW - Aluminum

KW - Catalysis

KW - Cyclization

KW - Hidden boron catalysis

KW - Hidden Brønsted acid catalysis

KW - Homogenous

KW - Oxidation

KW - Reduction

UR - https://www.scopus.com/pages/publications/85175388196

U2 - 10.1016/B978-0-12-820206-7.00052-4

DO - 10.1016/B978-0-12-820206-7.00052-4

M3 - Encyclopaedia / Dictionary Entry

AN - SCOPUS:85175388196

SN - 9780323913508

VL - 11

SP - 335

EP - 381

BT - Comprehensive Organometallic Chemistry IV

A2 - Liptrot, David J.

PB - Elsevier

ER -

Aluminum Complexes in Organic Synthesis

Abstract

Keywords

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