Alternation of Chemoselective Control in Stille-Heck and Heck-Stille Reaction Sequences

Kye-Simeon Masters, Bernard Luke Flynn

Research output: Contribution to journalArticleResearchpeer-review

11 Citations (Scopus)

Abstract

Sequential and one-pot Stille-Heck and Heck-Stille reaction processes have been invoked to give divergent access to polycyclic ring systems. Both reaction conditions and substrate structure are important in determining the nature of the reaction products formed. The Heck-Stille reactions have involved a reversal of the usual Heck regioselectivity and both cine- and ipso-substitutions have been observed in the Stille reaction.
Original languageEnglish
Pages (from-to)530 - 536
Number of pages7
JournalAdvanced Synthesis and Catalysis
Volume351
Issue number4
Publication statusPublished - 2009

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