Alternating 5,5-Dimethylcyclopentadiene and Diketopyrrolopyrrole Copolymer Prepared at Room Temperature for High Performance Organic Thin-Film Transistors

Zhuping Fei, Lei Chen, Yang Han, Eliot Gann, Anthony S. R. Chesman, Christopher R. McNeill, Thomas D. Anthopoulos, Martin Heeney, Agostino Pietrangelo

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35 Citations (Scopus)

Abstract

We report that the inclusion of nonaromatic 5,5-dimethylcyclopentadiene monomer into a conjugated backbone is an attractive strategy to high performance semiconducting polymers. The use of this monomer enables a room temperature Suzuki copolymerization with a diketopyrrolopyrrole comonomer to afford a highly soluble, high molecular weight material. The resulting low band gap polymer exhibits excellent photo and thermal stability, and despite a large π-π stacking distance of 4.26 Å, it demonstrates excellent performance in thin-film transistor devices.

Original languageEnglish
Pages (from-to)8094-8097
Number of pages4
JournalJournal of the American Chemical Society
Volume139
Issue number24
DOIs
Publication statusPublished - 21 Jun 2017

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