Allylic rearrangements during the rhodium-catalysed reactions of 2-allyloxybenzylamines and 2-(N-allyl-N-benzylamino)benzylamine

Eva M. Campl, W. Roy Jackson, Quentin J. McCubbin, Andrew E. Trnacek

Research output: Contribution to journalArticleResearchpeer-review

25 Citations (Scopus)

Abstract

Reactions of 2-allyloxybenzylamines with H2/CO in the presence of rhodium catalysts give 1,3-benzoxazines via a reaction which involves allylic cleavage and carbonylation as demonstrated by crossover experiments.

Original languageEnglish
Number of pages1
JournalJournal of the Chemical Society, Chemical Communications
Issue number24
DOIs
Publication statusPublished - 1 Dec 1994

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