Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau

David J Harding; Wasinee Phonsri; Phimphaka Harding; Keith Spencer Murray; Boujemaa Moubaraki; Guy N L Jameson

doi:10.1039/c4dt03184a

Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau

David J Harding
, Wasinee Phonsri
, Phimphaka Harding
, Keith Spencer Murray
, Boujemaa Moubaraki
, Guy N L Jameson

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

75 Citations (Scopus)

Abstract

[Fe(qsal-Br)2]NO3?2MeOH is reported which undergoes abrupt two step symmetry breaking spin crossover, T1/2(1st step) = 136 K and T1/2(2nd step) = 232 K with a hysteresis of 16 K and 5 K, respectively, and an unprecedented [HS-LS] plateau of 96 K.

Original language	English
Pages (from-to)	15079-15082
Number of pages	4
Journal	Dalton Transactions
Volume	44
Issue number	34
DOIs	https://doi.org/10.1039/c4dt03184a
Publication status	Published - 2015

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10.1039/c4dt03184a

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title = "Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau",

abstract = "[Fe(qsal-Br)2]NO3?2MeOH is reported which undergoes abrupt two step symmetry breaking spin crossover, T1/2(1st step) = 136 K and T1/2(2nd step) = 232 K with a hysteresis of 16 K and 5 K, respectively, and an unprecedented [HS-LS] plateau of 96 K.",

author = "Harding, \{David J\} and Wasinee Phonsri and Phimphaka Harding and Murray, \{Keith Spencer\} and Boujemaa Moubaraki and Jameson, \{Guy N L\}",

year = "2015",

doi = "10.1039/c4dt03184a",

language = "English",

volume = "44",

pages = "15079--15082",

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publisher = "The Royal Society of Chemistry",

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T1 - Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau

AU - Harding, David J

AU - Phonsri, Wasinee

AU - Harding, Phimphaka

AU - Murray, Keith Spencer

AU - Moubaraki, Boujemaa

AU - Jameson, Guy N L

PY - 2015

Y1 - 2015

N2 - [Fe(qsal-Br)2]NO3?2MeOH is reported which undergoes abrupt two step symmetry breaking spin crossover, T1/2(1st step) = 136 K and T1/2(2nd step) = 232 K with a hysteresis of 16 K and 5 K, respectively, and an unprecedented [HS-LS] plateau of 96 K.

AB - [Fe(qsal-Br)2]NO3?2MeOH is reported which undergoes abrupt two step symmetry breaking spin crossover, T1/2(1st step) = 136 K and T1/2(2nd step) = 232 K with a hysteresis of 16 K and 5 K, respectively, and an unprecedented [HS-LS] plateau of 96 K.

UR - http://pubs.rsc.org/en/content/articlepdf/2015/dt/c4dt03184a

U2 - 10.1039/c4dt03184a

DO - 10.1039/c4dt03184a

M3 - Article

SN - 1477-9226

VL - 44

SP - 15079

EP - 15082

JO - Dalton Transactions

JF - Dalton Transactions

IS - 34

ER -

Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau

Abstract

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Multifunctional hybrid spin crossover materials

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Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau

Abstract

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Multifunctional hybrid spin crossover materials

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