A utilization of choline chloride-based deep eutectic solvent integrated with alkaline earth metal hexahydrate in the pretreatment of oil palm fronds

Eng Kein New, Ta Yeong Wu, Khai Shing Voon, Alessandra Procentese, Katrina Pui Yee Shak, Wen Hui Teoh, Jun Wei Lim, Jamaliah Md. Jahim

    Research output: Contribution to journalArticleResearchpeer-review

    Abstract

    Over the past decade, deep eutectic solvents (DESs) have been touted as promising reagents in biomass valorization. This study focused on the novel utilization of type II choline chloride (ChCl)-based DESs by integrating group II metal chloride hexahydrate, namely, calcium chloride hexahydrate (CaCl2·6H2O) and magnesium chloride hexahydrate (MgCl2·6H2O) as the hydrogen bond donors for the pretreatment of oil palm fronds (OPF). Under atmospheric conditions, pretreatment with ChCl:CaCl2·6H2O (125 °C and 4.5 h) resulted in dual biomass valorization effects with a delignification of 46.51%, followed by xylose recovery and xylan removal at 54.12% and 78.67%, respectively. Such performance of ChCl:CaCl2·6H2O as a pretreatment solvent expedited the enzymatic glucose (59.31%) and total reducing sugar (63.89%) conversion in the OPF at a subsequent stage. Thus, the characterizations of pretreated OPF samples endorsed the application of type II ChCl-based DESs, particularly, ChCl:CaCl2·6H2O as a propitious approach for ligno-hemicellulose removal in pretreatment.

    Original languageEnglish
    Pages (from-to)2011-2026
    Number of pages16
    JournalIndustrial and Engineering Chemistry Research
    Volume60
    Issue number5
    DOIs
    Publication statusPublished - 10 Feb 2021

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