A study of the major gas-phase tautomer of adenine by microwave spectroscopy

Ronald D. Brown; Peter D. Godfrey; Donald McNaughton; Anthony P. Pierlot

doi:10.1016/0009-2614(89)87081-2

A study of the major gas-phase tautomer of adenine by microwave spectroscopy

Ronald D. Brown, Peter D. Godfrey, Donald McNaughton, Anthony P. Pierlot

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

127 Citations (Scopus)

Abstract

The microwave spectrum of the nucleic acid base adenine in a cw seeded supersonic beam has been analyzed indicating that the amino, N (9) H tautomer is the most stable in an isolated environment. A comparison of the experimental rotational constants is made with those obtained using ab initio 3-21G basis SCF calculations for three of the lower- energy tautomers.

Original language	English
Pages (from-to)	61-63
Number of pages	3
Journal	Chemical Physics Letters
Volume	156
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(89)87081-2
Publication status	Published - 24 Mar 1989

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10.1016/0009-2614(89)87081-2

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title = "A study of the major gas-phase tautomer of adenine by microwave spectroscopy",

abstract = "The microwave spectrum of the nucleic acid base adenine in a cw seeded supersonic beam has been analyzed indicating that the amino, N (9) H tautomer is the most stable in an isolated environment. A comparison of the experimental rotational constants is made with those obtained using ab initio 3-21G basis SCF calculations for three of the lower- energy tautomers.",

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AU - Godfrey, Peter D.

AU - McNaughton, Donald

AU - Pierlot, Anthony P.

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Y1 - 1989/3/24

N2 - The microwave spectrum of the nucleic acid base adenine in a cw seeded supersonic beam has been analyzed indicating that the amino, N (9) H tautomer is the most stable in an isolated environment. A comparison of the experimental rotational constants is made with those obtained using ab initio 3-21G basis SCF calculations for three of the lower- energy tautomers.

AB - The microwave spectrum of the nucleic acid base adenine in a cw seeded supersonic beam has been analyzed indicating that the amino, N (9) H tautomer is the most stable in an isolated environment. A comparison of the experimental rotational constants is made with those obtained using ab initio 3-21G basis SCF calculations for three of the lower- energy tautomers.

UR - https://www.scopus.com/pages/publications/0002216975

U2 - 10.1016/0009-2614(89)87081-2

DO - 10.1016/0009-2614(89)87081-2

M3 - Article

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EP - 63

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

ER -

A study of the major gas-phase tautomer of adenine by microwave spectroscopy

Abstract

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