A stannylene/aryl iodide reagent for allylic CH activation and double bond addition chemistry

Ajdin Kavara; Kandarpa D. Cousineau; Ahleah D. Rohr; Jeff W. Kampf; Mark M Banaszak Holl

doi:10.1021/om8000108

A stannylene/aryl iodide reagent for allylic CH activation and double bond addition chemistry

Ajdin Kavara, Kandarpa D. Cousineau, Ahleah D. Rohr, Jeff W. Kampf, Mark M Banaszak Holl

Research output: Contribution to journal › Article › Research › peer-review

27 Citations (Scopus)

Abstract

Allylic CH bond activation and addition across the C=C double bond are both observed in the reactions of alkenes with a stannylene/phenyl iodide reagent. The relative amounts of each of these products are sensitive to the steric bulk of the alkene and of the aryl halide.

Original language	English
Pages (from-to)	1041-1043
Number of pages	3
Journal	Organometallics
Volume	27
Issue number	6
DOIs	https://doi.org/10.1021/om8000108
Publication status	Published - 24 Mar 2008
Externally published	Yes

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10.1021/om8000108

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title = "A stannylene/aryl iodide reagent for allylic CH activation and double bond addition chemistry",

abstract = "Allylic CH bond activation and addition across the C=C double bond are both observed in the reactions of alkenes with a stannylene/phenyl iodide reagent. The relative amounts of each of these products are sensitive to the steric bulk of the alkene and of the aryl halide.",

author = "Ajdin Kavara and Cousineau, {Kandarpa D.} and Rohr, {Ahleah D.} and Kampf, {Jeff W.} and Holl, {Mark M Banaszak}",

year = "2008",

month = mar,

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doi = "10.1021/om8000108",

language = "English",

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journal = "Organometallics",

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T1 - A stannylene/aryl iodide reagent for allylic CH activation and double bond addition chemistry

AU - Kavara, Ajdin

AU - Cousineau, Kandarpa D.

AU - Rohr, Ahleah D.

AU - Kampf, Jeff W.

AU - Holl, Mark M Banaszak

PY - 2008/3/24

Y1 - 2008/3/24

N2 - Allylic CH bond activation and addition across the C=C double bond are both observed in the reactions of alkenes with a stannylene/phenyl iodide reagent. The relative amounts of each of these products are sensitive to the steric bulk of the alkene and of the aryl halide.

AB - Allylic CH bond activation and addition across the C=C double bond are both observed in the reactions of alkenes with a stannylene/phenyl iodide reagent. The relative amounts of each of these products are sensitive to the steric bulk of the alkene and of the aryl halide.

UR - http://www.scopus.com/inward/record.url?scp=41749104003&partnerID=8YFLogxK

U2 - 10.1021/om8000108

DO - 10.1021/om8000108

M3 - Article

AN - SCOPUS:41749104003

SN - 0276-7333

VL - 27

SP - 1041

EP - 1043

JO - Organometallics

JF - Organometallics

IS - 6

ER -

A stannylene/aryl iodide reagent for allylic CH activation and double bond addition chemistry

Abstract

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