A single-bonded cationic terminal borylene complex

Dragoslav Vidovic; Michael Findlater; Gregor Reeske; Alan H. Cowley

doi:10.1039/b609475a

A single-bonded cationic terminal borylene complex

Dragoslav Vidovic, Michael Findlater, Gregor Reeske, Alan H. Cowley

Research output: Contribution to journal › Article › Research › peer-review

29 Citations (Scopus)

Abstract

The cationic terminal borylene complex [(η⁵-C ₅H₅)(CO)₂FeB(η⁵-C ₅Me₅)][AlCl₄] has been isolated from the reaction of [(η⁵-C₅H₅)(CO) ₂FeB(Cl)(η¹-C₅Me₅)] with AlCl₃ and on the basis of X-ray crystallographic data, spectroscopic data and a DFT calculation it is concluded that the B→Fe bond order is one.

Original language	English
Pages (from-to)	3786-3787
Number of pages	2
Journal	Chemical Communications
Issue number	36
DOIs	https://doi.org/10.1039/b609475a
Publication status	Published - 21 Sept 2006
Externally published	Yes

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title = "A single-bonded cationic terminal borylene complex",

abstract = "The cationic terminal borylene complex [(η5-C 5H5)(CO)2FeB(η5-C 5Me5)][AlCl4] has been isolated from the reaction of [(η5-C5H5)(CO) 2FeB(Cl)(η1-C5Me5)] with AlCl3 and on the basis of X-ray crystallographic data, spectroscopic data and a DFT calculation it is concluded that the B→Fe bond order is one.",

author = "Dragoslav Vidovic and Michael Findlater and Gregor Reeske and Cowley, {Alan H.}",

year = "2006",

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doi = "10.1039/b609475a",

language = "English",

pages = "3786--3787",

journal = "Chemical Communications",

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T1 - A single-bonded cationic terminal borylene complex

AU - Vidovic, Dragoslav

AU - Findlater, Michael

AU - Reeske, Gregor

AU - Cowley, Alan H.

PY - 2006/9/21

Y1 - 2006/9/21

N2 - The cationic terminal borylene complex [(η5-C 5H5)(CO)2FeB(η5-C 5Me5)][AlCl4] has been isolated from the reaction of [(η5-C5H5)(CO) 2FeB(Cl)(η1-C5Me5)] with AlCl3 and on the basis of X-ray crystallographic data, spectroscopic data and a DFT calculation it is concluded that the B→Fe bond order is one.

AB - The cationic terminal borylene complex [(η5-C 5H5)(CO)2FeB(η5-C 5Me5)][AlCl4] has been isolated from the reaction of [(η5-C5H5)(CO) 2FeB(Cl)(η1-C5Me5)] with AlCl3 and on the basis of X-ray crystallographic data, spectroscopic data and a DFT calculation it is concluded that the B→Fe bond order is one.

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U2 - 10.1039/b609475a

DO - 10.1039/b609475a

M3 - Article

AN - SCOPUS:33748683192

SN - 1359-7345

SP - 3786

EP - 3787

JO - Chemical Communications

JF - Chemical Communications

IS - 36

ER -

A single-bonded cationic terminal borylene complex

Abstract

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