A silver(I) coordination polymer with bridging bis(thiosemicarbazone) ligands and unsupported argentophilic interactions

Sophie A. Crouch; Patrick R.W.J. Davey; Craig M. Forsyth; Stuart R. Batten; Brett M. Paterson

doi:10.1080/00958972.2022.2092845

A silver(I) coordination polymer with bridging bis(thiosemicarbazone) ligands and unsupported argentophilic interactions

Sophie A. Crouch, Patrick R.W.J. Davey, Craig M. Forsyth, Stuart R. Batten, Brett M. Paterson

School of Chemistry

Research output: Contribution to journal › Article › Research › peer-review

Abstract

The synthesis and structural characterization of a silver(I) coordination polymer is reported. The structure contains a silver(I) ion coordinated by three sulfur donor atoms from three bridging bis(thiosemicarbazone) ligands in a trigonal planar coordination environment, generating a 2-D coordination polymer. The structure involves hydrogen bonds between the tetrafluoroborate counterion and the ligands and close Ag⋅⋅⋅Ag contacts to create an overall 3-D network.

Original language	English
Pages (from-to)	1691-1701
Number of pages	11
Journal	Journal of Coordination Chemistry
Volume	75
Issue number	11-14
DOIs	https://doi.org/10.1080/00958972.2022.2092845
Publication status	Published - 5 Jul 2022

Keywords

3-D network
argentophilic
bis(thiosemicarbazone)
coordination polymer
Silver

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10.1080/00958972.2022.2092845

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title = "A silver(I) coordination polymer with bridging bis(thiosemicarbazone) ligands and unsupported argentophilic interactions",

abstract = "The synthesis and structural characterization of a silver(I) coordination polymer is reported. The structure contains a silver(I) ion coordinated by three sulfur donor atoms from three bridging bis(thiosemicarbazone) ligands in a trigonal planar coordination environment, generating a 2-D coordination polymer. The structure involves hydrogen bonds between the tetrafluoroborate counterion and the ligands and close Ag⋅⋅⋅Ag contacts to create an overall 3-D network.",

keywords = "3-D network, argentophilic, bis(thiosemicarbazone), coordination polymer, Silver",

author = "Crouch, \{Sophie A.\} and Davey, \{Patrick R.W.J.\} and Forsyth, \{Craig M.\} and Batten, \{Stuart R.\} and Paterson, \{Brett M.\}",

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doi = "10.1080/00958972.2022.2092845",

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T1 - A silver(I) coordination polymer with bridging bis(thiosemicarbazone) ligands and unsupported argentophilic interactions

AU - Crouch, Sophie A.

AU - Davey, Patrick R.W.J.

AU - Forsyth, Craig M.

AU - Batten, Stuart R.

AU - Paterson, Brett M.

PY - 2022/7/5

Y1 - 2022/7/5

N2 - The synthesis and structural characterization of a silver(I) coordination polymer is reported. The structure contains a silver(I) ion coordinated by three sulfur donor atoms from three bridging bis(thiosemicarbazone) ligands in a trigonal planar coordination environment, generating a 2-D coordination polymer. The structure involves hydrogen bonds between the tetrafluoroborate counterion and the ligands and close Ag⋅⋅⋅Ag contacts to create an overall 3-D network.

AB - The synthesis and structural characterization of a silver(I) coordination polymer is reported. The structure contains a silver(I) ion coordinated by three sulfur donor atoms from three bridging bis(thiosemicarbazone) ligands in a trigonal planar coordination environment, generating a 2-D coordination polymer. The structure involves hydrogen bonds between the tetrafluoroborate counterion and the ligands and close Ag⋅⋅⋅Ag contacts to create an overall 3-D network.

KW - 3-D network

KW - argentophilic

KW - bis(thiosemicarbazone)

KW - coordination polymer

KW - Silver

UR - https://www.scopus.com/pages/publications/85133486829

U2 - 10.1080/00958972.2022.2092845

DO - 10.1080/00958972.2022.2092845

M3 - Article

AN - SCOPUS:85133486829

SN - 0095-8972

VL - 75

SP - 1691

EP - 1701

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

IS - 11-14

ER -

A silver(I) coordination polymer with bridging bis(thiosemicarbazone) ligands and unsupported argentophilic interactions

Abstract

Keywords

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