A Self-Assembled CO2 Reduction Electrocatalyst: Posy-Bouquet-Shaped Gold-Polyaniline Core-Shell Nanocomposite

Amruthalakshmi Vijayakumar, Yong Zhao, Jinshuo Zou, Kezhong Wang, Chong Yong Lee, Douglas R. MacFarlane, Caiyun Wang, Gordon G. Wallace

Research output: Contribution to journalArticleResearchpeer-review

1 Citation (Scopus)

Abstract

Here it was demonstrated that the decoration of gold (Au) with polyaniline is an effective approach in increasing its electrocatalytic reduction of CO2 to CO. The core-shell-structured gold-polyaniline (Au−PANI) nanocomposite delivered a CO2-to-CO conversion efficiency of 85 % with a high current density of 11.6 mA cm−2. The polyaniline shell facilitated CO2 adsorption, and the subsequent formation of reaction intermediates on the gold core contributed to the high efficiency observed.

Original languageEnglish
Pages (from-to)5023-5030
Number of pages8
JournalChemSusChem
Volume13
Issue number18
DOIs
Publication statusAccepted/In press - 18 Sep 2020

Keywords

  • carbon dioxide reduction
  • catalyst
  • gold
  • nanocomposite
  • polyaniline

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